米贝霉素G的全合成:C(1) -C(10)片段的合成

Simon R. Bailey, A. Teerawutgulrag, E. Thomas
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引用次数: 7

摘要

羟基丁烯内酯5是5-甲氧基a-米贝霉素的C(1) - C(10)片段的前体,通过对羟基环己酮8的立体和区域选择性修饰合成。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Total synthesis of milbemycin G: synthesis of the C(1)–C(10) fragment
The hydroxybutenolide 5, a precursor of the C(1)–C(10) fragment of the 5-methoxy a-miibemycins, is synthesised by stereo- and regio-selective modification of the hydroxycyclohexanone 8.
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