强碱中的有机反应。第五部分环氧化物和醚的碱熔合

Journal of The Chemical Society C: Organic Pub Date : 1971-01-01 DOI:10.1039/J39710001840

M. Ansell, I. Shepherd, B. Weedon

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引用次数: 3

摘要

从长链环氧酸的碱融合得到的结果表明，至少发生了四种不同的反应途径，其中β-消除反应似乎是新的未活化的环氧化合物。这种特殊的反应也可以发生在简单的丙烯酸醚上，例如11-烷氧十一烷酸。

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Organic reactions in strong alkalis. Part V. Alkali fusion of epoxides and ethers

The results obtained from the alkali fusion of long-chain epoxy-acids indicate the occurrence of at least four different reaction pathways, one of which, a β-elimination reaction, appears to be novel for unactivated epoxides. This particular reaction is also shown to occur with simple acylic ethers, as exemplified by 11-alkoxyundecanoic acids.

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Journal of The Chemical Society C: Organic

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