油棕空果串(EFB)流化床气化制氢研究

S. Shahlan, K. Kidam, T. Abdullah, M. W. Ali, L. Pejic, H. Kamarden
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引用次数: 2

摘要

马来西亚是最大的棕榈油生产国之一,该行业在马来西亚的经济增长中发挥着重要作用。随着这个行业的发展壮大,产生了大量的油棕废物,造成了生物质废物超载的问题。由于油棕废料有许多重要的用途,如空果束(EFB),生产氢气作为可再生能源的兴趣也在增加。流化床反应器内的气化过程是生产氢气最常用和最有利的热化学工艺。尽管对使用EFB生产氢气的有效性进行了大量的实验研究,但在工业上的过程实施仍然令人沮丧。这是由于缺乏成熟的技术和高资本投资成本。本研究采用ASPEN PLUS (v. 8.8)仿真软件,对流化床气化炉内EFB气化过程进行了数值模拟,优化了气化温度、气化压力,研究了气化过程中的化学行为差异。结果表明,温度升高会增加氢气的产量,提高碳的转化效率。最佳温度和压力分别为850℃和1.035 bar。结果表明,经过多次气体净化,焦炭得到了明显的去除。纯化氢气的最终产品为14.5 kg/hr,约为氢气产量的21%。结果表明,EFB在未来具有作为一种能源使用的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Hydrogen Gas Production from Gasification of Oil Palm Empty Fruit Bunch (EFB) in a Fluidized Bed Reactor
Malaysia is one of the largest producers of palm oil and this industry plays an important role in Malaysia economic growth. As this industry grows larger, a significant amount of oil palm waste is generated, creating the problem of overloading biomass waste. Since the oil palm waste has many significant uses such as empty fruit bunches (EFB), the interest in production of hydrogen gas as the renewable energy from EFB also increases. The most common and favorable thermochemical processes to produce the hydrogen gas is gasification process in fluidized bed reactor. Regardless of tremendous experimental studies done on effectiveness of using EFB for production of hydrogen, the process implementation in industry is still discouraging. This is due to lack of proven technology and high capital cost of investment.  In this study, a computational modeling was developed for EFB gasification in fluidized bed gasifier using the ASPEN PLUS simulator (v. 8.8) to optimize the gasification temperature, pressure and to study the different of chemical behavior. The results indicated that increase in temperature will increases the production of hydrogen and enhances carbon conversion efficiency. The optimum temperature and pressure was 850 °C and 1.035 bar respectively. The result shows that the char was removed significantly after several gas cleaning process. The final product for purified hydrogen gas is 14.5 kg/hr which is around 21% of hydrogen yield. Based on the result, it indicates that EFB has a potential to be used as a source of energy in a future.
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