{"title":"新型delafosite型CuInO2的离子交换合成及结构","authors":"M. Shimode, Y. Hayashi, M. Sasaki, K. Mukaida","doi":"10.2320/MATERTRANS1989.41.1111","DOIUrl":null,"url":null,"abstract":"New delafossite-type CuInO 2 was synthesized by ion exchange reaction of CuCl with α-NaFeO 2 -type NaInO 2 or with α-LiFeO 2 -type LiInO 2 . According to the XRD, after 144 h the main product obtained at 623 K was CuInO 2 in either starting material. Lattice parameters of CuInO 2 derived from NaInO 2 or LiInO 2 as determined by Rietveld analysis, are a = 329.01 pin, c = 1738.8 pm, and a = 329.22 pm, c = 1738.8 pm, respectively.","PeriodicalId":18264,"journal":{"name":"Materials Transactions Jim","volume":"42 1","pages":"1111-1113"},"PeriodicalIF":0.0000,"publicationDate":"2000-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"11","resultStr":"{\"title\":\"Ion Exchange Synthesis and Structure of New Delafossite-Type CuInO2\",\"authors\":\"M. Shimode, Y. Hayashi, M. Sasaki, K. Mukaida\",\"doi\":\"10.2320/MATERTRANS1989.41.1111\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"New delafossite-type CuInO 2 was synthesized by ion exchange reaction of CuCl with α-NaFeO 2 -type NaInO 2 or with α-LiFeO 2 -type LiInO 2 . According to the XRD, after 144 h the main product obtained at 623 K was CuInO 2 in either starting material. Lattice parameters of CuInO 2 derived from NaInO 2 or LiInO 2 as determined by Rietveld analysis, are a = 329.01 pin, c = 1738.8 pm, and a = 329.22 pm, c = 1738.8 pm, respectively.\",\"PeriodicalId\":18264,\"journal\":{\"name\":\"Materials Transactions Jim\",\"volume\":\"42 1\",\"pages\":\"1111-1113\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2000-09-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"11\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Transactions Jim\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2320/MATERTRANS1989.41.1111\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Transactions Jim","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2320/MATERTRANS1989.41.1111","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 11
摘要
通过CuCl与α-NaFeO - 2型naino2或α- lifeo2型LiInO - 2离子交换反应，合成了新的延迟岩型CuInO - 2。XRD结果表明，在623 K下，144h后得到的主要产物均为CuInO 2。通过Rietveld分析，由naino2和LiInO 2得到的CuInO 2晶格参数分别为a = 329.01 pin, c = 1738.8 pm, a = 329.22 pm, c = 1738.8 pm。
Ion Exchange Synthesis and Structure of New Delafossite-Type CuInO2
New delafossite-type CuInO 2 was synthesized by ion exchange reaction of CuCl with α-NaFeO 2 -type NaInO 2 or with α-LiFeO 2 -type LiInO 2 . According to the XRD, after 144 h the main product obtained at 623 K was CuInO 2 in either starting material. Lattice parameters of CuInO 2 derived from NaInO 2 or LiInO 2 as determined by Rietveld analysis, are a = 329.01 pin, c = 1738.8 pm, and a = 329.22 pm, c = 1738.8 pm, respectively.
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