Mechanism-Based Modeling of Long-Term Degradation

The use of composites in high-temperature, long-lifetime applications requires a basic understanding of composite degradation mechanisms, advances in analytical capabilities, and accurate accelerated and scaled tests. To advance all of these goals, models are proposed based on a variety of fundamental material mechanisms. Thermal, oxygen, and moisture diffusion, chemical reactions, composite micromechanics, modified laminated plate theory, and fracture mechanics based damage models are used. All models are designed to stay as simple and fundamental as possible. All are coupled, so that interactions between various effects are modeled implicitly. Ongoing efforts at MIT are reviewed here, with some reference to other work, but no attempt is made to do a comprehensive review. Mechanism-based models are yielding an understanding of the mechanisms behind observed degradation phenomena, helping to design accelerated tests, and are the first steps toward a predictive capability.