响应面法优化麻疯树生物柴油生产工艺

Nurudeen Ishola Mohammed, N. Kabbashi, Z. Alam, M. Mirghani
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引用次数: 7

摘要

生物柴油的成本主要由原料、生产过程和材料等因素决定。显然,与化石柴油相比,最终的生物柴油产品有点贵。虽然人们已经提出了以麻疯树等高含油量的非食品原料来降低原料成本,但一种很有前途的两步加氢酯化方法可能会抵消高游离脂肪酸油资源的生产成本。最重要的是,材料和工艺的优化有望减少浪费,提高产品纯度并产生更少的废水。然而,优化产品生成一直是令人生畏的难以捉摸的,因为需要从整体上考虑几个参数。本研究采用响应面法(RSM)优化麻疯树水解产物的产率和转化率。两种反应的最佳产率和转化率均为96%,最佳温度为60°C,催化剂负载为4 wt%,反应时间为6小时。研究结果表明,利用design Expert 6.0.8的面中心复合设计优化麻疯树水解产物的产率和脂肪酸甲酯转化率,可以保证产品的纯度,节约能源,减少废弃物的产生,为生物柴油的定价提供了重要的前沿。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Optimization of Jatropha Biodiesel Production by Response Surface Methodology
Cost of biodiesel is primarily because of factors such as the feedstock, production process and materials. Apparently, the final biodiesel product is a bit expensive compared to fossil diesel fuel. While non-food feedstock of high oil content such as Jatropha curcas has been proposed to reduce the cost due to the feedstock, a promising two-step approach of hydro-esterification can possibly offset the production cost for oil resource with high free fatty acids. Most importantly, optimization of the materials and process is expected to reduce wastage, enhance product purity and generate less wastewater. However, optimizing product generation has been dauntingly elusive because several parameters are needed to be considered holistically. In this study, Response Surface Methodology (RSM) was employed to optimize the yield and conversion of Jatropha biodiesel from J. curcas hydrolysate. An optimum Yield and conversion of 96% was achieved for both responses with an optimum temperature value of 60°C, 4 wt% for catalyst loading for 6 hrs reaction time. Findings imply that optimization study of Jatropha curcas hydrolysate for yield and conversion of fatty acid methyl esters using face centered central composite design of Design Expert 6.0.8 can ensure purity of product, conserve energy and reduce waste generation providing a significant frontier in biodiesel pricing.
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