{"title":"星际介质和彗星物质中氨基自由基(NH2)的LVG分析","authors":"Mohit K. Sharma","doi":"10.1016/j.molap.2019.04.001","DOIUrl":null,"url":null,"abstract":"<div><p>Amidogen (NH<sub>2</sub>), a <em>b</em><span><span>-type asymmetric top molecule with electric dipole moment 1.82 ± 0.05 Debye, is detected in Sgr B2, in high-mass star-forming regions W31C (G10.6−0.4), W49N (G43.2−0.1), W51 (G49.5−0.4), G34.3+0.1, and in several comets. Because of two </span>hydrogen atoms<span><span>, each with nuclear spin 1/2, its rotational energy levels can be classified into ortho and para groups. We have not considered for fine structure splitting and hyper-fine structure splitting of rotational levels. For 15 rotational levels in the ground </span>vibrational state, having energy up to 400 cm</span></span><span><math><mrow><msup><mrow></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup><mo>,</mo></mrow></math></span> for each specie, the energies of rotational levels, and Einstein <em>A</em> and <em>B</em><span><span> coefficients for radiative transitions<span> between the levels are calculated, using accurate values of spectroscopic data. These radiative transition probabilities along with the </span></span>collisional<span> rate coefficients (obtained from a scaling law) are employed as input parameters for solving a set of statistical equilibrium equations<span> coupled with the equations of radiative transfer for each group. Several emission lines produced by amidogen are found. For each species of NH</span></span></span><sub>2</sub>, we have considered some strongest emission lines along with the observed one, which may help for identification of NH<sub>2</sub><span> in the interstellar medium (ISM) and in the cometary material.</span></p></div>","PeriodicalId":44164,"journal":{"name":"Molecular Astrophysics","volume":"15 ","pages":"Pages 1-7"},"PeriodicalIF":0.0000,"publicationDate":"2019-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.molap.2019.04.001","citationCount":"7","resultStr":"{\"title\":\"LVG analysis of amidogen radical (NH2) found in interstellar medium and in cometary material\",\"authors\":\"Mohit K. Sharma\",\"doi\":\"10.1016/j.molap.2019.04.001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Amidogen (NH<sub>2</sub>), a <em>b</em><span><span>-type asymmetric top molecule with electric dipole moment 1.82 ± 0.05 Debye, is detected in Sgr B2, in high-mass star-forming regions W31C (G10.6−0.4), W49N (G43.2−0.1), W51 (G49.5−0.4), G34.3+0.1, and in several comets. Because of two </span>hydrogen atoms<span><span>, each with nuclear spin 1/2, its rotational energy levels can be classified into ortho and para groups. We have not considered for fine structure splitting and hyper-fine structure splitting of rotational levels. For 15 rotational levels in the ground </span>vibrational state, having energy up to 400 cm</span></span><span><math><mrow><msup><mrow></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup><mo>,</mo></mrow></math></span> for each specie, the energies of rotational levels, and Einstein <em>A</em> and <em>B</em><span><span> coefficients for radiative transitions<span> between the levels are calculated, using accurate values of spectroscopic data. These radiative transition probabilities along with the </span></span>collisional<span> rate coefficients (obtained from a scaling law) are employed as input parameters for solving a set of statistical equilibrium equations<span> coupled with the equations of radiative transfer for each group. Several emission lines produced by amidogen are found. For each species of NH</span></span></span><sub>2</sub>, we have considered some strongest emission lines along with the observed one, which may help for identification of NH<sub>2</sub><span> in the interstellar medium (ISM) and in the cometary material.</span></p></div>\",\"PeriodicalId\":44164,\"journal\":{\"name\":\"Molecular Astrophysics\",\"volume\":\"15 \",\"pages\":\"Pages 1-7\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/j.molap.2019.04.001\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Molecular Astrophysics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2405675818300435\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"Physics and Astronomy\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Molecular Astrophysics","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2405675818300435","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"Physics and Astronomy","Score":null,"Total":0}
LVG analysis of amidogen radical (NH2) found in interstellar medium and in cometary material
Amidogen (NH2), a b-type asymmetric top molecule with electric dipole moment 1.82 ± 0.05 Debye, is detected in Sgr B2, in high-mass star-forming regions W31C (G10.6−0.4), W49N (G43.2−0.1), W51 (G49.5−0.4), G34.3+0.1, and in several comets. Because of two hydrogen atoms, each with nuclear spin 1/2, its rotational energy levels can be classified into ortho and para groups. We have not considered for fine structure splitting and hyper-fine structure splitting of rotational levels. For 15 rotational levels in the ground vibrational state, having energy up to 400 cm for each specie, the energies of rotational levels, and Einstein A and B coefficients for radiative transitions between the levels are calculated, using accurate values of spectroscopic data. These radiative transition probabilities along with the collisional rate coefficients (obtained from a scaling law) are employed as input parameters for solving a set of statistical equilibrium equations coupled with the equations of radiative transfer for each group. Several emission lines produced by amidogen are found. For each species of NH2, we have considered some strongest emission lines along with the observed one, which may help for identification of NH2 in the interstellar medium (ISM) and in the cometary material.
期刊介绍:
Molecular Astrophysics is a peer-reviewed journal containing full research articles, selected review articles, and thematic issues. Molecular Astrophysics is a new journal where researchers working in planetary and exoplanetary science, astrochemistry, astrobiology, spectroscopy, physical chemistry and chemical physics can meet and exchange their ideas. Understanding the origin and evolution of interstellar and circumstellar molecules is key to understanding the Universe around us and our place in it and has become a fundamental goal of modern astrophysics. Molecular Astrophysics aims to provide a platform for scientists studying the chemical processes that form and dissociate molecules, and control chemical abundances in the universe, particularly in Solar System objects including planets, moons, and comets, in the atmospheres of exoplanets, as well as in regions of star and planet formation in the interstellar medium of galaxies. Observational studies of the molecular universe are driven by a range of new space missions and large-scale scale observatories opening up. With the Spitzer Space Telescope, the Herschel Space Observatory, the Atacama Large Millimeter/submillimeter Array (ALMA), NASA''s Kepler mission, the Rosetta mission, and more major future facilities such as NASA''s James Webb Space Telescope and various missions to Mars, the journal taps into the expected new insights and the need to bring the various communities together on one platform. The journal aims to cover observational, laboratory as well as computational results in the galactic, extragalactic and intergalactic areas of our universe.