{"title":"双齿硫代氨基脲铜配合物的合成、磁性及波谱研究","authors":"S. Chandra, U. Kumar","doi":"10.1081/SIM-200026270","DOIUrl":null,"url":null,"abstract":"Abstract The synthesis and spectral characterization of new copper(II) complexes of the composition CuL2X2 [where L = 2‐methylcyclohexanone thiosemicarbazone (L1) and 4 N‐methyl thiosemi‐carbazone (L2) and X = Cl, NO3, and 0.5SO4] are reported. All the complexes have been characterized by IR, electronic, EPR, and mass spectral studies, magnetic moments, and conductivity measurements. A tetragonal geometry has been assigned to all the complexes except the sulfato complexes which were found to have five coordinated square‐pyramidal geometry.","PeriodicalId":22160,"journal":{"name":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","volume":"56 1","pages":"1417 - 1430"},"PeriodicalIF":0.0000,"publicationDate":"2004-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"Synthesis, Magnetic and Spectral Studies on Copper(II) Complexes with Bidentate Thiosemicarbazones\",\"authors\":\"S. Chandra, U. Kumar\",\"doi\":\"10.1081/SIM-200026270\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract The synthesis and spectral characterization of new copper(II) complexes of the composition CuL2X2 [where L = 2‐methylcyclohexanone thiosemicarbazone (L1) and 4 N‐methyl thiosemi‐carbazone (L2) and X = Cl, NO3, and 0.5SO4] are reported. All the complexes have been characterized by IR, electronic, EPR, and mass spectral studies, magnetic moments, and conductivity measurements. A tetragonal geometry has been assigned to all the complexes except the sulfato complexes which were found to have five coordinated square‐pyramidal geometry.\",\"PeriodicalId\":22160,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"volume\":\"56 1\",\"pages\":\"1417 - 1430\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2004-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1081/SIM-200026270\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic and Metal-organic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/SIM-200026270","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 6
摘要
摘要报道了新型铜(II)配合物CuL2X2的合成和光谱表征[其中L = 2‐甲基环己酮硫代氨基卡巴酮(L1)和4n‐甲基硫代氨基卡巴酮(L2)， X = Cl, NO3和0.5SO4]。所有配合物都通过IR，电子，EPR和质谱研究，磁矩和电导率测量进行了表征。除了磺胺配合物外，所有配合物都具有四边形几何形状，磺胺配合物具有五个协调的方锥体几何形状。
Synthesis, Magnetic and Spectral Studies on Copper(II) Complexes with Bidentate Thiosemicarbazones
Abstract The synthesis and spectral characterization of new copper(II) complexes of the composition CuL2X2 [where L = 2‐methylcyclohexanone thiosemicarbazone (L1) and 4 N‐methyl thiosemi‐carbazone (L2) and X = Cl, NO3, and 0.5SO4] are reported. All the complexes have been characterized by IR, electronic, EPR, and mass spectral studies, magnetic moments, and conductivity measurements. A tetragonal geometry has been assigned to all the complexes except the sulfato complexes which were found to have five coordinated square‐pyramidal geometry.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
