不同绿色缓蚀剂和不同转速对碳钢在原油中的缓蚀性能的评价

Abbas Kh. Ibrahim Algburi
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摘要

腐蚀是石油工业中的一个主要问题,它经常发生在原油生产设备和石油产品运输管道上。为了保护这些部件不受腐蚀,不断注入大量的抑制剂,这些抑制剂逐渐在金属表面形成一层蓬松的抑制剂,从而保护金属不受腐蚀。近年来,缓蚀剂对环境的影响越来越受到人们的重视和关注。与环境有关的新条例已被指定,将有毒化学品的使用改为使用所谓的“绿色化学品”。在API比重为30.6的原油介质中,采用不同浓度的玉米油、葵花籽油、亚麻籽油、蓖麻油等不同的绿色缓蚀剂,转速分别为0、500、1250、2000转/分,在100 ~ 400 ppm范围内对碳钢进行了防腐试验。减重结果表明,原油中碳钢的腐蚀速率随着缓蚀剂浓度的增加而降低,而与转速的增加相对应。结果表明,在浓度为400 ppm、转速为0 rpm、环境温度为25℃的条件下,对玉米油、葵花籽油、亚麻籽油和蓖麻油的抑制效果最佳,分别为41.85%、50.76%、63.55%和92.63%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Evaluation of Corrosion Inhibition of Carbon Steel in Crude Oil by Using Different Green Corrosion Inhibitors and Various Rotation Speeds
Corrosion is a major problem in the petroleum industry, which often occurs to crude oil production equipment and to petroleum product transportation pipelines as well. In order to protect these parts from corrosion, much small quantities of inhibitors are constantly injected, which gradually formulate a fluffy layer of inhibitor over the metal surface so as to protect it from corrosion. Recently, the impact of corrosion inhibitors on the environment has been raising more attention and concern. New regulations related to environment have been designated, imposing a change in the use of toxic chemicals to the utilization of the so-called “green chemicals”. Experiments on carbon steel corrosion protection have been conducted in a medium of crude oil has an API gravity of 30.6 by using different concentrations, ranging between 100 – 400 ppm of different green inhibitors such as corn oil, sunflower oil, flaxseed oil and castor oil with a different rotation speeds, namely, 0, 500, 1250 and 2000 rpm. The weight loss outcomes have showed that the rate of carbon steel corrosion in the crude oil decreases with the rise of inhibitors’ concentration, while corresponds with the increase of the rotational speed. In addition, it was found that the maximum inhibition efficiency achieved for the inhibitors corn oil, sunflower oil, flaxseed oil and castor oil in crude oil was using a concentration of 400 ppm, a rotation speed of 0 rpm and an ambient temperature (25 °C) is 41.85%, 50.76%, 63.55% and 92.63%, respectively.
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