改善PM与NOx同步还原系统的NOx还原性能研究

S. Itabashi, Kuniaki Niimi, S. Kamoshita, Akira Shoji, T. Oda, Shinya Hirota, Tetsuo Watanabe
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引用次数: 5

摘要

对柴油微粒和氮氧化物减少系统(DPNR)的性能改进进行了研究,该系统可以同时减少柴油发动机尾气中的氮氧化物和颗粒物(PM)。实验系统(以下简称“双DPNR”)由并联布置的两个DPNR催化剂组成,每个催化剂的下游均设有排气节流阀,控制废气流向催化剂,外加一个喷油器,精确控制空燃比和催化剂床层温度。喷油器用于向DPNR催化剂提供丰富的混合物,并通过交替操作排气节流阀在两种催化剂之间切换废气流量。试验是在发动机稳定运行状态下进行的。结果表明,氮氧化物还原性能显著提高,降低了氮氧化物还原造成的燃油经济性损失。这是通过使用排气节流阀来降低催化剂上的比速度(SV)比来实现的,从而在最佳时间长度内保持丰富的气氛。双DPNR系统还有望在PM强制氧化过程中提高NOx还原性能,这是传统系统难以做到的,并且还可以提高因硫引起的催化剂中毒的回收性能。商业化的主要问题是处理瞬态操作。在本文中,催化剂的耐久性也被报道为附录中DPNR的主要问题。具体而言,使用量产发动机进行了相当于25万公里运行的长期耐久性评估。这是为了通过减少催化剂中储存的氮氧化物的数量来澄清燃料中硫浓度的影响,以及堵塞催化剂的低灰分油的影响。研究已经获得了DPNR催化剂在商用车上使用的基本数据,这需要更好的催化剂性能和耐久性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study of Improvements in NOx Reduction Performance on Simultaneous Reduction System of PM and NOx
Performance improvements were studied for the diesel particulate and NOx reduction system (DPNR), a system that simultaneously reduces NOx and Particulate Matter (PM) from diesel engine exhaust gas. The experimental system (hereinafter called the "dual DPNR") consists of two DPNR catalysts arranged in parallel, each provided with an exhaust throttle valve downstream to control the exhaust gas flow to the catalyst, plus a fuel injector that precisely controls the air-fuel ratio and the catalyst bed temperature. The fuel injector is used to supply a rich mixture to the DPNR catalyst, and the flow of exhaust gas is switched between the two catalysts by operating the exhaust throttle valves alternately. Tests were conducted with the engine running at steady state. The results indicated that the NOx reduction performance dramatically improved and the loss of fuel economy from the NOx reduction reduced. This was achieved by using the exhaust throttle valve to lower the Specific Velocity (SV) ratio on the catalyst therefore maintaining a rich atmosphere for the optimum length of time. The dual DPNR system is also expected to improve NOx reduction performance during forced PM oxidation, which is difficult for a conventional system, and also to improve recovery performance from catalyst poisoning due to sulfur. The main issues for commercialization are dealing with transient operation. In this paper, the durability of the catalyst is also reported as the major issue of DPNR in the APPENDIX. Specifically, a long-term endurance evaluation equivalent to 250,000km running was carried out using a mass-production engine. This was to clarify the effects of the sulfur concentration in the fuel by reducing the amount of NOx stored in the catalyst, as well as the effects of low-ash oil that clogged the catalyst. Research has yielded basic data on the use of DPNR catalysts in commercial vehicles which require better catalyst performance and durability.
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