{"title":"醋酸酐在流动和静态体系中的热分解动力学","authors":"P. G. Blake, A. Speis","doi":"10.1039/J29710001877","DOIUrl":null,"url":null,"abstract":"The thermal decomposition of gaseous acetic anhydride has been studied in flow and static apparata between 197 and 370°C. The decomposition, which yields keten and acetic acid only, is homogeneous and unimolecular, k= 1011·27 exp (–134,700/RT) s–1.","PeriodicalId":17268,"journal":{"name":"Journal of The Chemical Society B: Physical Organic","volume":"69 1","pages":"1877-1878"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Kinetics of thermal decomposition of acetic anhydride in flow and static systems\",\"authors\":\"P. G. Blake, A. Speis\",\"doi\":\"10.1039/J29710001877\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The thermal decomposition of gaseous acetic anhydride has been studied in flow and static apparata between 197 and 370°C. The decomposition, which yields keten and acetic acid only, is homogeneous and unimolecular, k= 1011·27 exp (–134,700/RT) s–1.\",\"PeriodicalId\":17268,\"journal\":{\"name\":\"Journal of The Chemical Society B: Physical Organic\",\"volume\":\"69 1\",\"pages\":\"1877-1878\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society B: Physical Organic\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J29710001877\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society B: Physical Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J29710001877","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Kinetics of thermal decomposition of acetic anhydride in flow and static systems
The thermal decomposition of gaseous acetic anhydride has been studied in flow and static apparata between 197 and 370°C. The decomposition, which yields keten and acetic acid only, is homogeneous and unimolecular, k= 1011·27 exp (–134,700/RT) s–1.
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