{"title":"声波振动对液相化学反应动力学的影响","authors":"T. P. Kulagina, L. Smirnov, Andrianova Zs","doi":"10.15406/MOJBOC.2018.02.00074","DOIUrl":null,"url":null,"abstract":"Where γ is some structure-sensitive coefficient and σ changes as σ=Р0sin(2πvt). At the initial stage, the formation of dimmers is governed by the value of k(v)–i. It is almost convenient to create in a reaction system the density fluctuation, uniform in space, at the expense of external periodic force, influencing system an acoustic wave. At the action of a acoustic wave with a frequency v the stretching σ and compression created in system lead to change of kinetic constants k(v)-and destruction of associates. This constant has view:","PeriodicalId":18674,"journal":{"name":"MOJ Bioorganic & Organic Chemistry","volume":"03 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2018-06-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Influence of acoustic vibrations on the kinetics of liquid-phase chemical reactions involving associates\",\"authors\":\"T. P. Kulagina, L. Smirnov, Andrianova Zs\",\"doi\":\"10.15406/MOJBOC.2018.02.00074\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Where γ is some structure-sensitive coefficient and σ changes as σ=Р0sin(2πvt). At the initial stage, the formation of dimmers is governed by the value of k(v)–i. It is almost convenient to create in a reaction system the density fluctuation, uniform in space, at the expense of external periodic force, influencing system an acoustic wave. At the action of a acoustic wave with a frequency v the stretching σ and compression created in system lead to change of kinetic constants k(v)-and destruction of associates. This constant has view:\",\"PeriodicalId\":18674,\"journal\":{\"name\":\"MOJ Bioorganic & Organic Chemistry\",\"volume\":\"03 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-06-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"MOJ Bioorganic & Organic Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.15406/MOJBOC.2018.02.00074\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"MOJ Bioorganic & Organic Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.15406/MOJBOC.2018.02.00074","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Influence of acoustic vibrations on the kinetics of liquid-phase chemical reactions involving associates
Where γ is some structure-sensitive coefficient and σ changes as σ=Р0sin(2πvt). At the initial stage, the formation of dimmers is governed by the value of k(v)–i. It is almost convenient to create in a reaction system the density fluctuation, uniform in space, at the expense of external periodic force, influencing system an acoustic wave. At the action of a acoustic wave with a frequency v the stretching σ and compression created in system lead to change of kinetic constants k(v)-and destruction of associates. This constant has view:
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