Nidhi Kalgotra, Bhawana Gupta, Savit Andotra, Sandeep Kumar, S. Pandey
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引用次数: 2
摘要
以氯化锌(ZnCl2)为原料，在水溶液中与甲苯/苯二硫代碳酸盐CS2Na钠盐反应，以1:2的摩尔比合成了甲苯/苯二硫代碳酸锌[(CH3C6H4和C6H5CH2OCS2)2Zn]。这些配合物进一步与氮和磷供体配体反应，得到供体稳定的配合物[[(CH3C6H4和C6H5CH2)OCS2]2Zn。nL]， (L = Bipy, Phen for and PPh3, Py for)。这些配合物通过元素分析、质量、红外和核磁共振(1H、13C和31P)光谱进行了表征。热分析(TGA/DTA)，循环伏安法和扫描电镜也进行了。提出了围绕Zn(II)金属的扭曲四面体和八面体几何形状。这些复合物具有潜在的抗菌和抗真菌活性。
Synthesis, Spectral, Thermal, Electrochemical, and Biocidal Activity of Tolyl/Benzyl Dithiocarbonates of Zinc(II)
Tolyl/benzyl dithiocarbonates of zinc(II) [(CH3C6H4 and C6H5CH2OCS2)2Zn] have been synthesized in 1 : 2 molar ratio by the reaction of zinc chloride, ZnCl2, with sodium salts of tolyl/benzyl dithiocarbonates CS2Na, in aqueous medium. These complexes were further reacted with nitrogen and phosphorous donor ligands to obtain donor stabilized complex of the type [[(CH3C6H4 and C6H5CH2)OCS2]2Zn.nL], (L = Bipy, Phen for and PPh3, Py for ). These complexes were characterised by elemental analysis, mass, IR, and NMR (1H, 13C, and 31P) spectroscopies. The thermal analysis (TGA/DTA), cyclic voltammetry, and SEM have also been done. Distorted tetrahedral and octahedral geometries around the Zn(II) metal are proposed. These complexes have depicted potential antibacterial and antifungal activity.
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