测定二正丁基4,7,10-三氧aundecylstannane向伯烷基自由基转移氢的速率常数

Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry Pub Date : 2001-07-01 DOI:10.1016/S1387-1609(01)01267-1

Fouad Ferkous , Marie Degueil-Castaing , Hervé Deleuze , Bernard Maillard

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摘要

通过研究4,7,10-三氧十一烷基二丁基锡烷对6-溴-1-己烯自由基的还原作用，确定了该锡烷在不同温度下氢向伯烷基自由基转移的速率常数。这项工作表明，该化合物是三丁基丁氢化物的优良替代品

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Détermination de la constante de vitesse de transfert d’hydrogène par le di-n-butyl 4,7,10-trioxaundécylstannane aux radicaux alkyle primaires

The rate constant of hydrogen transfer by dibutyl 4,7,10-trioxaundecylstannane to primary alkyl radicals was determined at different temperatures by the study of the free radical reduction of 6-bromo-1-hexene by this stannane. This work shows that this compound is an excellent substitute to tri-n-butyltinhydride

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Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry

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