富镍镍钛基合金中Ni - 16Ti - 11相的鉴定

Sean H. Mills, Yu Hong, B. Kappes, R. Noebe, M. A. Zaeem, A. Stebner, B. Amin-ahmadi
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引用次数: 0

摘要

最近报道在NiTi和NiTiNb合金中存在的“立方Ni3Ti2”沉淀相也记录在Ni56Ti36Hf8合金中时效形成。利用透射电子显微镜和初始密度泛函理论技术,更精确地确定了相为Ni16Ti11,具有pm3m空间群的对称性,晶格参数a = 8.816 Å。在这种结构中,镍原子优先分离到54原子单元胞的周长晶格位置。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Identification of a Ni 16Ti 11 Precipitate Phase within Nickel-Rich, Nickel-Titanium-Based Alloys
A "cubic Ni3Ti2" precipitate phase recently reported to exist within NiTi and NiTiNb alloys is documented to also form within a Ni56Ti36Hf8 alloy upon aging. Using transmission electron microscopy and ab intio density functional theory techniques, the phase is more precisely identified to be Ni16Ti11 with symmetry of the pm3m space group and a lattice parameter a = 8.816 Å. In this structure, nickel atoms preferentially segregate to the perimeter lattice sites of the 54-atom unit cell.
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