M.P.Sridhar Kumar, B. Viswanathan, C.S. Swamy, V. Srinivasan
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Interaction of carbon monoxide with the hydrogen storage alloy, CaNi5; kinetic and surface studies
Impurities in hydrogen affect the storage capacity of intermetallic systems. Carbon monoxide interacts with nickel-containing intermetallics such as CaNi5 to give volatile nickel carbonyl which leads to a fall in the transition metal content, the hydrogen storage capacity and the sorption kinetics. The implications of these effects are investigated here by X-ray Photoelectron Spectroscopy (XPS) and sorption kinetic data.
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