化学百慕大三角

Dumitru Petru I. Iga, D. Popescu, V. Niculescu
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引用次数: 1

摘要

人们相信,百慕大三角能够隐藏人类看到的进入该区域的物体。化学中的百慕大三角能够隐藏(掩盖)原子或被对称镜面切割的平面分子碎片,不是人眼的,而是偏振光的。一个三角形的骨架(框架)已被设想,具有覆盖数百个分子式的能力,提供后者指脂肪族或部分脂肪族化合物,并且具有低程度的氧化。这个骨架(框架)基于一个非常普遍和强大的原则,适用于中观实体。提出了从分子式中产生的同分异构体可以有四种类型(基团):中介体,C2对称(CTS),不规则手性(irchi)和构象(构成)。揭示了以下普遍规律:所有的CTS和irchi都可以转化为中位体,但反之则不成立,至少对同一骨架而言是如此。同时,令人印象深刻的结构天然或合成组合具有至少一种实际或设想的中位异构体的特征。因此,从结构的角度来看,中位异构体可以作为参考化合物。上述原理已应用于许多天然化合物:氨基酸、脂类、碳水化合物、核苷、维生素、类固醇、生物碱、碳氢化合物。提出了一个支持三角表示的数学方程。有人提出了四种类型中哪一种是上层的问题。对这个问题作了初步的回答。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Bermuda Triangle in Chemistry
It is believed that the place called Bermuda triangle is able to hide of human seeing objects entered its area. A Bermuda triangle in chemistry is able to hide (mask) atoms or planar molecular fragments cut by their mirror plane of symmetry, not of human eyes but, of polarized light. A triangular skeleton (frame) has been imagined, possessing the ability to cover many hundreds of molecular formulae, providing the latter refer to aliphatic, or partially aliphatic, compounds, and with a low degree of oxidation. This skeleton (frame) is based on a very general and strong principle, valid in meso entities. The idea is advanced that isomers coming up from a molecular formula could be of four types (groups): meso, C2 symmetrical (CTS), irrechi (from irregular chiral) and constitutional (constit.). The following universal rule is revealed: all CTS and irrechi can be converted to meso ones, but the reverse is not true, at least for the same skeleton. At the same time, an impressive number of constitutional natural or synthetic combinations are characterized by at least one real or envisaged meso isomer. Thus, from a structural point of view, meso isomers are justified as reference compounds. The above mentioned principles have been applied to numerous natural compounds: amino acids, lipids, carbohydrates, nucleosides, vitamins, steroids, alkaloids,  hydrocarbons. A mathematical equation sustaining the triangular representation has been proposed. One raises the question which of the four types is the upper. A tentative answer is given to this question.
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