水溶性客体对包合物水合物晶体生长的影响

Kazuya Ozawa, Takao Shibata, R. Ohmura
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引用次数: 0

摘要

本文报道了笼形物水合物在四氢吡喃(THP)和甲烷气体饱和的液态水中晶体生长行为和晶体形态的目视观察。THP是部分水溶性客体物质。结果表明,甲烷+ THP +水体系中水合物的晶体生长行为与甲烷+水体系相比有较大的变化,与混合气体+水溶性离子客体物质+水体系相比也有较大的变化。水合物最初在水- THP界面形成。形成的水合物被生长到一定的尺寸,然后从水- THP界面分离。水- THP界面保持不变,然后不断重复水合物的形成。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effects of Water Soluble Guest on Clathrate Hydrate Crystal Growth
This study reports on the visual observations of the crystal growth behavior and the crystal morphology of clathrate hydrate in liquid water presaturated with the tetrahydropyran (THP) and the methane gas. THP is the partially water soluble guest substance. It was observed that the crystal growth behavior of the hydrate in methane + THP + water system greatly changed compared to those in methane + water system, and also those in the mixed gas + water soluble ionic guest substance + water system. The hydrate was initially formed at the water – THP interface. The formed hydrate was grew to a certain size and then detached from the water ‐ THP interface. The water – THP interface was maintained and then the hydrate formation was continually repeated.
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