气相色谱-原子发射检测法分析空气中丁基锡氯化物。

AIHAJ : a journal for the science of occupational and environmental health and safety Pub Date : 2000-11-01 DOI:10.1080/15298660008984592

L. M. Allan, D. Verma, F. Yang, Y. Chau, R. Maguire

{"title":"气相色谱-原子发射检测法分析空气中丁基锡氯化物。","authors":"L. M. Allan, D. Verma, F. Yang, Y. Chau, R. Maguire","doi":"10.1080/15298660008984592","DOIUrl":null,"url":null,"abstract":"An initial screening test compared the use of tropolone (2-hydroxy-2,4-6-cycloheptatrienone) in acetic acid with sodium diethyldithiocarbamate (NaDDC) as chelating agents for the extraction of butyltin chlorides from glass fiber filters and XAD-2 resin tube. NaDDC was chosen for subsequent analyses. Mono-, di-, and tributyltin chloride were spiked onto glass fiber filters and XAD-2 resin, extracted in toluene with NaDDC and derivatized with pentylmagnesium bromide. Derivatized butyltin species were determined by gas chromatography with plasma atomic emission detection. Glass fiber filters and XAD-2 resin were found to provide high retention of butyltin compounds during sampling and efficient recovery of butyltin compounds by extraction with NaDDC.","PeriodicalId":7449,"journal":{"name":"AIHAJ : a journal for the science of occupational and environmental health and safety","volume":"61 1","pages":"820-4"},"PeriodicalIF":0.0000,"publicationDate":"2000-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"A method for the analysis of butyltin chlorides in air by gas chromatography with atomic emission detection.\",\"authors\":\"L. M. Allan, D. Verma, F. Yang, Y. Chau, R. Maguire\",\"doi\":\"10.1080/15298660008984592\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"An initial screening test compared the use of tropolone (2-hydroxy-2,4-6-cycloheptatrienone) in acetic acid with sodium diethyldithiocarbamate (NaDDC) as chelating agents for the extraction of butyltin chlorides from glass fiber filters and XAD-2 resin tube. NaDDC was chosen for subsequent analyses. Mono-, di-, and tributyltin chloride were spiked onto glass fiber filters and XAD-2 resin, extracted in toluene with NaDDC and derivatized with pentylmagnesium bromide. Derivatized butyltin species were determined by gas chromatography with plasma atomic emission detection. Glass fiber filters and XAD-2 resin were found to provide high retention of butyltin compounds during sampling and efficient recovery of butyltin compounds by extraction with NaDDC.\",\"PeriodicalId\":7449,\"journal\":{\"name\":\"AIHAJ : a journal for the science of occupational and environmental health and safety\",\"volume\":\"61 1\",\"pages\":\"820-4\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2000-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"AIHAJ : a journal for the science of occupational and environmental health and safety\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15298660008984592\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"AIHAJ : a journal for the science of occupational and environmental health and safety","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15298660008984592","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 1

摘要

初步筛选比较了醋酸中的tropolone(2-羟基-2,4-6-环庚三烯酮)与二乙基二硫代氨基甲酸钠(NaDDC)作为螯合剂对玻璃纤维过滤器和XAD-2树脂管中丁基锡氯化物的萃取效果。后续分析选择NaDDC。将一丁基锡、二丁基锡和三丁基锡加到玻璃纤维过滤器和XAD-2树脂上，用NaDDC在甲苯中提取，用溴化戊基镁衍生化。用气相色谱-等离子体原子发射检测法测定了衍生丁基锡的种类。玻璃纤维过滤器和XAD-2树脂在取样过程中提供了较高的丁基锡化合物保留率，并通过NaDDC提取有效地回收了丁基锡化合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

A method for the analysis of butyltin chlorides in air by gas chromatography with atomic emission detection.

An initial screening test compared the use of tropolone (2-hydroxy-2,4-6-cycloheptatrienone) in acetic acid with sodium diethyldithiocarbamate (NaDDC) as chelating agents for the extraction of butyltin chlorides from glass fiber filters and XAD-2 resin tube. NaDDC was chosen for subsequent analyses. Mono-, di-, and tributyltin chloride were spiked onto glass fiber filters and XAD-2 resin, extracted in toluene with NaDDC and derivatized with pentylmagnesium bromide. Derivatized butyltin species were determined by gas chromatography with plasma atomic emission detection. Glass fiber filters and XAD-2 resin were found to provide high retention of butyltin compounds during sampling and efficient recovery of butyltin compounds by extraction with NaDDC.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

AIHAJ : a journal for the science of occupational and environmental health and safety

自引率

0.00%

发文量