玻子理论与二元硅酸盐和硼酸盐玻璃熔体两层液不混相的关系

L. W. Tilton
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引用次数: 1

摘要

富硅和富硼二元玻璃类似于羧酸盐,它们具有宿主空腔,其中改性氧化物可以作为无活性物质被包裹在其中而没有应力,直到空腔大约被填满。额外的改性会在基体的孔洞和玻璃体的空腔中产生应力。然后结构开始瓦解,混合发生。所需的摩尔百分比修正量用如下的方程表示
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Relation of vitron theory to 2-layer-liquid immiscibility in binary silicate and borate glass melts
Silica-rich and boron-rich binary glasses resemble c1athrates in having host cavities in which modifier oxides may be inclosed without stress as inactive gues ts until the cavities are approximately fill ed. Additional modification results in stress both in the holes of the matrix and the cavities of vitrons. Then the structur e begins to disintegrate and mixing takes place. The r equired mole-percent modification is expressed by an equation of the form
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