{"title":"一种新型异质结CuWO4/g-C3N4光催化剂在可见光下去除有机污染物","authors":"D. Dang, S. Le, Hai Huy Nguyen","doi":"10.25073/2588-1140/vnunst.5559","DOIUrl":null,"url":null,"abstract":"In this study, a series of CuWO4/g-C3N4 composites were synthesized using a facile construction method. The structural characteristics of the composites were examined using various techniques, including XRD, SEM, SEM-EDS, FT-IR, and UV–DRS. The photocatalytic performance of the CuWO4/g-C3N4 nanocomposites was evaluated in the degradation of methylene blue (MB) under visible light irradiation. The findings revealed that the CuWO4/g-C3N4 composite with a mass ratio of 10% CuWO4 displayed the highest efficiency (89%) in degrading MB during an 80-minute photodegradation process, which was consistent with the pseudo-first-order kinetics. These results clearly demonstrate that the formation of a Z-scheme CuWO4/g-C3N4 heterojunction significantly improves the photocatalytic efficiency by promoting rapid separation of electron-hole pairs and enhancing the redox capability. Additionally, the photodegradation efficiency remained above 85% even after four cycles, suggesting the stability of the catalyst.","PeriodicalId":23524,"journal":{"name":"VNU Journal of Science: Natural Sciences and Technology","volume":"72 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2023-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A Novel Heterojunction CuWO4/g-C3N4 Photocatalyst for Removal of Organic Pollutant under Visible Light Irradiation\",\"authors\":\"D. Dang, S. Le, Hai Huy Nguyen\",\"doi\":\"10.25073/2588-1140/vnunst.5559\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this study, a series of CuWO4/g-C3N4 composites were synthesized using a facile construction method. The structural characteristics of the composites were examined using various techniques, including XRD, SEM, SEM-EDS, FT-IR, and UV–DRS. The photocatalytic performance of the CuWO4/g-C3N4 nanocomposites was evaluated in the degradation of methylene blue (MB) under visible light irradiation. The findings revealed that the CuWO4/g-C3N4 composite with a mass ratio of 10% CuWO4 displayed the highest efficiency (89%) in degrading MB during an 80-minute photodegradation process, which was consistent with the pseudo-first-order kinetics. These results clearly demonstrate that the formation of a Z-scheme CuWO4/g-C3N4 heterojunction significantly improves the photocatalytic efficiency by promoting rapid separation of electron-hole pairs and enhancing the redox capability. Additionally, the photodegradation efficiency remained above 85% even after four cycles, suggesting the stability of the catalyst.\",\"PeriodicalId\":23524,\"journal\":{\"name\":\"VNU Journal of Science: Natural Sciences and Technology\",\"volume\":\"72 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-06-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"VNU Journal of Science: Natural Sciences and Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.25073/2588-1140/vnunst.5559\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"VNU Journal of Science: Natural Sciences and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.25073/2588-1140/vnunst.5559","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A Novel Heterojunction CuWO4/g-C3N4 Photocatalyst for Removal of Organic Pollutant under Visible Light Irradiation
In this study, a series of CuWO4/g-C3N4 composites were synthesized using a facile construction method. The structural characteristics of the composites were examined using various techniques, including XRD, SEM, SEM-EDS, FT-IR, and UV–DRS. The photocatalytic performance of the CuWO4/g-C3N4 nanocomposites was evaluated in the degradation of methylene blue (MB) under visible light irradiation. The findings revealed that the CuWO4/g-C3N4 composite with a mass ratio of 10% CuWO4 displayed the highest efficiency (89%) in degrading MB during an 80-minute photodegradation process, which was consistent with the pseudo-first-order kinetics. These results clearly demonstrate that the formation of a Z-scheme CuWO4/g-C3N4 heterojunction significantly improves the photocatalytic efficiency by promoting rapid separation of electron-hole pairs and enhancing the redox capability. Additionally, the photodegradation efficiency remained above 85% even after four cycles, suggesting the stability of the catalyst.