{"title":"电位滴定法研究锡(II)-氟化物络合物的形成","authors":"D. Djokić-Konstantinovska, B. Zmbova","doi":"10.1016/0020-708X(85)90010-9","DOIUrl":null,"url":null,"abstract":"<div><p>The purpose of present investigation was to determine optimal condition for obtaining a stable Sn(II) complex with sodium flouride.</p><p>Measurements were performed by a potentiometric titration method, using a selective electrode with a flouride membrane, at pH 5, constant ionic strength and 22 ± 1°C. Stability constants were determined for both water and water-ethanol mixtures.</p><p>The obtained types of tin(II) complexes with flouride anion varied in dependence of Sn(II)/F molar ratio, which also influences the biological behavior of the tin colloid obtained by <sup>99<em>m</em></sup>Tc labelling of tin flouride complexes observed on experimental animals.</p></div>","PeriodicalId":22517,"journal":{"name":"The International journal of applied radiation and isotopes","volume":"36 8","pages":"Pages 669-671"},"PeriodicalIF":0.0000,"publicationDate":"1985-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-708X(85)90010-9","citationCount":"3","resultStr":"{\"title\":\"Investigation of the formation of tin(II)-flouride complex by potentiometric titration\",\"authors\":\"D. Djokić-Konstantinovska, B. Zmbova\",\"doi\":\"10.1016/0020-708X(85)90010-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The purpose of present investigation was to determine optimal condition for obtaining a stable Sn(II) complex with sodium flouride.</p><p>Measurements were performed by a potentiometric titration method, using a selective electrode with a flouride membrane, at pH 5, constant ionic strength and 22 ± 1°C. Stability constants were determined for both water and water-ethanol mixtures.</p><p>The obtained types of tin(II) complexes with flouride anion varied in dependence of Sn(II)/F molar ratio, which also influences the biological behavior of the tin colloid obtained by <sup>99<em>m</em></sup>Tc labelling of tin flouride complexes observed on experimental animals.</p></div>\",\"PeriodicalId\":22517,\"journal\":{\"name\":\"The International journal of applied radiation and isotopes\",\"volume\":\"36 8\",\"pages\":\"Pages 669-671\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1985-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-708X(85)90010-9\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The International journal of applied radiation and isotopes\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020708X85900109\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The International journal of applied radiation and isotopes","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020708X85900109","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Investigation of the formation of tin(II)-flouride complex by potentiometric titration
The purpose of present investigation was to determine optimal condition for obtaining a stable Sn(II) complex with sodium flouride.
Measurements were performed by a potentiometric titration method, using a selective electrode with a flouride membrane, at pH 5, constant ionic strength and 22 ± 1°C. Stability constants were determined for both water and water-ethanol mixtures.
The obtained types of tin(II) complexes with flouride anion varied in dependence of Sn(II)/F molar ratio, which also influences the biological behavior of the tin colloid obtained by 99mTc labelling of tin flouride complexes observed on experimental animals.
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