{"title":"整齐线性聚硅氧烷基离子聚合物:基于结构的性质修改和应用的见解","authors":"L. Poon, Jacob R. Hum, R. Weiss","doi":"10.3390/macromol1010002","DOIUrl":null,"url":null,"abstract":"A diverse range of linear polysiloxane-based ionic polymers that are hydrophobic and highly flexible can be obtained by substituting the polymers with varying amounts of ionic centers. The materials can be highly crystalline solids, amorphous soft solids, poly(ionic) liquids or viscous polymer liquids. A key to understanding how structural variations can lead to these different materials is the establishment of correlations between the physical (dynamic and static) properties and the structures of the polymers at different distance scales. This short review provides such correlations by examining the influence of structural properties (such as molecular weights, ion pair contents, and ion types) on key bulk properties of the materials.","PeriodicalId":18139,"journal":{"name":"Macromol","volume":"17 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2020-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"8","resultStr":"{\"title\":\"Neat Linear Polysiloxane-Based Ionic Polymers: Insights into Structure-Based Property Modifications and Applications\",\"authors\":\"L. Poon, Jacob R. Hum, R. Weiss\",\"doi\":\"10.3390/macromol1010002\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A diverse range of linear polysiloxane-based ionic polymers that are hydrophobic and highly flexible can be obtained by substituting the polymers with varying amounts of ionic centers. The materials can be highly crystalline solids, amorphous soft solids, poly(ionic) liquids or viscous polymer liquids. A key to understanding how structural variations can lead to these different materials is the establishment of correlations between the physical (dynamic and static) properties and the structures of the polymers at different distance scales. This short review provides such correlations by examining the influence of structural properties (such as molecular weights, ion pair contents, and ion types) on key bulk properties of the materials.\",\"PeriodicalId\":18139,\"journal\":{\"name\":\"Macromol\",\"volume\":\"17 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2020-12-21\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"8\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromol\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3390/macromol1010002\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromol","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/macromol1010002","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Neat Linear Polysiloxane-Based Ionic Polymers: Insights into Structure-Based Property Modifications and Applications
A diverse range of linear polysiloxane-based ionic polymers that are hydrophobic and highly flexible can be obtained by substituting the polymers with varying amounts of ionic centers. The materials can be highly crystalline solids, amorphous soft solids, poly(ionic) liquids or viscous polymer liquids. A key to understanding how structural variations can lead to these different materials is the establishment of correlations between the physical (dynamic and static) properties and the structures of the polymers at different distance scales. This short review provides such correlations by examining the influence of structural properties (such as molecular weights, ion pair contents, and ion types) on key bulk properties of the materials.
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