激光重熔Al-Cu共晶合金的快速凝固

M. Zimmermann , M. Carrard , W. Kurz
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引用次数: 187

摘要

使用高功率co2激光器对共晶al - 32.7% wt% Cu进行了快速表面再凝固,速度在0.2 ~ 8 m/s之间。通过激光迹线中心的纵向切割,利用透射电子显微镜观察微观结构的取向,测量了局部生长速率。随生长速率变化的显微组织有:(a)生长速率低于20 cm/s时,α-Al/θ-Al2Cu为规则的片层共晶结构,片层间距可达17 nm; (b)生长速率为20 ~ 50 cm/s时,α-Al/θ′-Al2Cu为新的波状共晶形貌;(c)生长速率大于50 cm/s时,α-Al固溶体与波状共晶交替形成的带状结构。对快速凝固条件下共晶生长的最新分析模型与实验结果进行了比较。与经典公式λ2Vs = const相反。关系预测随着生长速率的增加,晶粒间距会不断减小,这个新的理论模型清楚地预测了耦合共晶生长的极限,这与单相凝固的绝对稳定极限相类似。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Rapid solidification of Al-Cu eutectic alloy by laser remelting

Rapid surface resolidification using a high powered CO2-laser has been performed on eutectic Al-32.7 wt% Cu at speeds between 0.2 and 8 m/s. By means of longitudinal cuts through the centre of the laser trace, the local growth rate has been measured by observation of the orientation of the microstructure using transmission electron microscopy. The various microstructures as a function of growth rate, are:

  • 1.

    (a) regular lamellar eutectic α-Al/θ-Al2Cu structure for growth rates below 20 cm/s with interlamellar spacing as fine as 17 nm;

  • 2.

    (b) a new wavy eutectic α-Al/θ'-Al2Cu morphology for growth rates of between 20 and 50 cm/s;

  • 3.

    (c) a banded structure formed by alternating supersaturated α-Al solid solution and the wavy eutectic for growth rates greater than 50 cm/s.

A recent analytical model for eutectic growth under rapid solidification condition is compared to the experimental results. Contrary to the classical λ2Vs = const. relationship, which predicts a continuous decrease in spacing as the growth rate increases, this new theoretical model clearly predicts a limit for the coupled eutectic growth which finds its analogy in single phase solidification in the limit of absolute stability.
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