膨润土插层镍二酸催化牛油裂解生物柴油工艺研究

I. W. Sutapa, Dwi Astuti Kasmanto, Rosmawaty, M. Maahury
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引用次数: 2

摘要

牛油裂解生物柴油是一种生产生物汽油的方法。以牛油为原料,经酯化和酯交换反应制备生物柴油。裂解过程将产生碳链长度较轻的生物汽油(C4−C12)。本研究采用膨润土插层镍二酸催化剂进行裂解,缩短了裂解时间和使用温度。在600℃下煅烧2小时制备膨润土nicl2插层催化剂,并用SEM对其进行表征。裂解温度分别为450℃和500℃,用GC-MS对产物进行表征。色谱结果显示有新化合物的存在。新化合物为甲酸甲酯(C5H10O2);十一酸甲酯(C12H24O2);1、探索(C5H12O2);壬酸(C11H22O2)和1,2-二恶烷(C10H20O2)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Biodiesel cracking process from beef tallow using catalyst bentonite intercalated NiCl2
Biodiesel cracking from beef tallow is a method to produce biogasoline. The biodiesel from beef tallow obtain by esterification and transesterification reaction. The cracking process will produce biogasoline with carbon chain lengths that are lighter (C4−C12). In this study the cracking process is done using bentonite intercalated NiCl2 catalyst to shorten the time and the use of high temperatures. Production of bentonite NiCl2-intercalated catalyst calcined at a temperature of 600 °C for 2 hours and characterized using SEM. A cracking temperature was conducted at 450 °C and 500 °C, then the product characterized using GC-MS. The chromatogram’s result showed the presence of new compounds. The new compounds are methyl formate (C5H10O2); methyl undecanoate (C12H24O2); 1,3-propanediol (C5H12O2); nonanoic acid (C11H22O2), and 1,2-dioxolane (C10H20O2).
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