I. W. Sutapa, Dwi Astuti Kasmanto, Rosmawaty, M. Maahury
{"title":"膨润土插层镍二酸催化牛油裂解生物柴油工艺研究","authors":"I. W. Sutapa, Dwi Astuti Kasmanto, Rosmawaty, M. Maahury","doi":"10.1063/5.0059518","DOIUrl":null,"url":null,"abstract":"Biodiesel cracking from beef tallow is a method to produce biogasoline. The biodiesel from beef tallow obtain by esterification and transesterification reaction. The cracking process will produce biogasoline with carbon chain lengths that are lighter (C4−C12). In this study the cracking process is done using bentonite intercalated NiCl2 catalyst to shorten the time and the use of high temperatures. Production of bentonite NiCl2-intercalated catalyst calcined at a temperature of 600 °C for 2 hours and characterized using SEM. A cracking temperature was conducted at 450 °C and 500 °C, then the product characterized using GC-MS. The chromatogram’s result showed the presence of new compounds. The new compounds are methyl formate (C5H10O2); methyl undecanoate (C12H24O2); 1,3-propanediol (C5H12O2); nonanoic acid (C11H22O2), and 1,2-dioxolane (C10H20O2).","PeriodicalId":13712,"journal":{"name":"INTERNATIONAL CONFERENCE ON ENERGY AND ENVIRONMENT (ICEE 2021)","volume":"47 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Biodiesel cracking process from beef tallow using catalyst bentonite intercalated NiCl2\",\"authors\":\"I. W. Sutapa, Dwi Astuti Kasmanto, Rosmawaty, M. Maahury\",\"doi\":\"10.1063/5.0059518\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Biodiesel cracking from beef tallow is a method to produce biogasoline. The biodiesel from beef tallow obtain by esterification and transesterification reaction. The cracking process will produce biogasoline with carbon chain lengths that are lighter (C4−C12). In this study the cracking process is done using bentonite intercalated NiCl2 catalyst to shorten the time and the use of high temperatures. Production of bentonite NiCl2-intercalated catalyst calcined at a temperature of 600 °C for 2 hours and characterized using SEM. A cracking temperature was conducted at 450 °C and 500 °C, then the product characterized using GC-MS. The chromatogram’s result showed the presence of new compounds. The new compounds are methyl formate (C5H10O2); methyl undecanoate (C12H24O2); 1,3-propanediol (C5H12O2); nonanoic acid (C11H22O2), and 1,2-dioxolane (C10H20O2).\",\"PeriodicalId\":13712,\"journal\":{\"name\":\"INTERNATIONAL CONFERENCE ON ENERGY AND ENVIRONMENT (ICEE 2021)\",\"volume\":\"47 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-09-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"INTERNATIONAL CONFERENCE ON ENERGY AND ENVIRONMENT (ICEE 2021)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1063/5.0059518\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"INTERNATIONAL CONFERENCE ON ENERGY AND ENVIRONMENT (ICEE 2021)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1063/5.0059518","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Biodiesel cracking process from beef tallow using catalyst bentonite intercalated NiCl2
Biodiesel cracking from beef tallow is a method to produce biogasoline. The biodiesel from beef tallow obtain by esterification and transesterification reaction. The cracking process will produce biogasoline with carbon chain lengths that are lighter (C4−C12). In this study the cracking process is done using bentonite intercalated NiCl2 catalyst to shorten the time and the use of high temperatures. Production of bentonite NiCl2-intercalated catalyst calcined at a temperature of 600 °C for 2 hours and characterized using SEM. A cracking temperature was conducted at 450 °C and 500 °C, then the product characterized using GC-MS. The chromatogram’s result showed the presence of new compounds. The new compounds are methyl formate (C5H10O2); methyl undecanoate (C12H24O2); 1,3-propanediol (C5H12O2); nonanoic acid (C11H22O2), and 1,2-dioxolane (C10H20O2).