{"title":"大豆和葡萄籽油基聚合物的热表征:遵循绿色化学原理的新合成途径","authors":"M. V. D. Almeida, R. Alarcon, G. Bannach","doi":"10.18362/BJTA.V4.I3.223","DOIUrl":null,"url":null,"abstract":"Abstract This paper describes the synthesis of polymers from glycerol and vegetable oils as soybean and grape seed, synthesized following the principles of green chemistry. Simultaneous thermogravimetric analysis – differential thermal analysis (TG-DTA) and differential scanning calorimetry (DSC) were employed to evaluate the thermal decomposition, thermal stability, and oxidation, glass transition and crystallization processes. Hence it was possible to verify that they have glass transition near to room temperature. Therefore these polymers may be used as chemical slow release agents triggered by temperature and as thermal security tags. Trabalho SiAT 13 CARACTERIZACAO TERMICA DE POLIMEROS DE OLEO DE SOJA E UVA SINTETIZADO POR NOVA ROTA SINTETICA SEGUINDO PRINCIPIOS DA QUIMICA VERDE. Trabalho apresentado no VII SiAT – Simposio de Analise de Termica realizado no periodo de 19 a 21 de julho de 2015 em Bauru, na Faculdade de Ciencias – UNESP.","PeriodicalId":9282,"journal":{"name":"Brazilian Journal of Thermal Analysis","volume":"73 1","pages":"37-40"},"PeriodicalIF":0.0000,"publicationDate":"2015-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"THERMAL CARACTERIZATION OF SOYBEAN AND GRAPE SEED OIL-BASED POLYMERS: NEW SYNTHESIS PATHWAY FOLLOWING GREEN CHEMISTRY’S PRINCIPLES\",\"authors\":\"M. V. D. Almeida, R. Alarcon, G. Bannach\",\"doi\":\"10.18362/BJTA.V4.I3.223\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract This paper describes the synthesis of polymers from glycerol and vegetable oils as soybean and grape seed, synthesized following the principles of green chemistry. Simultaneous thermogravimetric analysis – differential thermal analysis (TG-DTA) and differential scanning calorimetry (DSC) were employed to evaluate the thermal decomposition, thermal stability, and oxidation, glass transition and crystallization processes. Hence it was possible to verify that they have glass transition near to room temperature. Therefore these polymers may be used as chemical slow release agents triggered by temperature and as thermal security tags. Trabalho SiAT 13 CARACTERIZACAO TERMICA DE POLIMEROS DE OLEO DE SOJA E UVA SINTETIZADO POR NOVA ROTA SINTETICA SEGUINDO PRINCIPIOS DA QUIMICA VERDE. Trabalho apresentado no VII SiAT – Simposio de Analise de Termica realizado no periodo de 19 a 21 de julho de 2015 em Bauru, na Faculdade de Ciencias – UNESP.\",\"PeriodicalId\":9282,\"journal\":{\"name\":\"Brazilian Journal of Thermal Analysis\",\"volume\":\"73 1\",\"pages\":\"37-40\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2015-10-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Brazilian Journal of Thermal Analysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.18362/BJTA.V4.I3.223\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Brazilian Journal of Thermal Analysis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.18362/BJTA.V4.I3.223","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
THERMAL CARACTERIZATION OF SOYBEAN AND GRAPE SEED OIL-BASED POLYMERS: NEW SYNTHESIS PATHWAY FOLLOWING GREEN CHEMISTRY’S PRINCIPLES
Abstract This paper describes the synthesis of polymers from glycerol and vegetable oils as soybean and grape seed, synthesized following the principles of green chemistry. Simultaneous thermogravimetric analysis – differential thermal analysis (TG-DTA) and differential scanning calorimetry (DSC) were employed to evaluate the thermal decomposition, thermal stability, and oxidation, glass transition and crystallization processes. Hence it was possible to verify that they have glass transition near to room temperature. Therefore these polymers may be used as chemical slow release agents triggered by temperature and as thermal security tags. Trabalho SiAT 13 CARACTERIZACAO TERMICA DE POLIMEROS DE OLEO DE SOJA E UVA SINTETIZADO POR NOVA ROTA SINTETICA SEGUINDO PRINCIPIOS DA QUIMICA VERDE. Trabalho apresentado no VII SiAT – Simposio de Analise de Termica realizado no periodo de 19 a 21 de julho de 2015 em Bauru, na Faculdade de Ciencias – UNESP.