沸石中的固态离子交换:第8部分。无水条件下氯化镧与沸石的相互作用

Bogdan Sulikowski , Josef Find, Hellmut G. Karge, Daniel Herein
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引用次数: 24

摘要

描述了在完全无水条件下,氯化镧与氢形式的铁素体、丝光沸石、L型沸石和faujasite的相互作用。采用原位红外和x射线衍射技术研究了相互作用的过程。没有发现LaCl3与小孔h -铁素体相互作用的证据。研究的其他三种结构即使在周围完全排除水或水蒸气的情况下也与LaCl3相互作用。讨论了沸石中固态离子交换的可能机理。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Solid-state ion exchange in zeolites: Part 8. Interaction of lanthanum(III) chloride with zeolites under anhydrous conditions

Interaction of lanthanum(III) chloride with hydrogen forms of ferrierite, mordenite, zeolite L, and faujasite, under completely anhydrous conditions, is described. The course of the interaction has been studied by in situ i.r. and XRD techniques. No evidence of interaction between LaCl3 and small-pore H-ferrierite was found. The other three structures investigated do interact with LaCl3 even under the complete exclusion of water or water vapor from the surroundings. Plausible mechanisms of the solid-state ion exchange in zeolites are also discussed.

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