温度梯度下石墨烯/SiR纳米复合材料的电树特性

Yimeng Li, B. Du, Jin Li, Zhonglei Li, T. Han, Z. Ran
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引用次数: 1

摘要

本文制备了填充量为0.001 ~ 0.005 wt %的石墨烯/硅橡胶(SiR)纳米复合材料,以提高在不同温度梯度下的电树抑制能力。通过控制高压侧和接地侧的温度,在三个温度梯度下进行电气树试验。实验结果表明,石墨烯含量为0.003 wt%的SiR样品具有最佳的电阻性能。随着石墨烯含量从0 wt %增加到0.003 wt %,树长和累积损伤均减少,但随着填料含量从0.003 wt %进一步增加到0.005 wt %,树长和累积损伤增加。负温度梯度下整齐SiR树廓呈圆形,正温度梯度下树廓呈三角形。然而,当石墨烯存在时,温度梯度的影响减弱。石墨烯的掺杂导致纳米片与聚合物基体之间的界面产生更深的陷阱位点,从而增强了SiR的电阻。该研究为抑制电缆附件中SiR的电树提供了一种有效的方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Electrical Tree Characteristics in Graphene/SiR Nanocomposites under Temperature Gradient
In this paper, graphene/silicone rubber (SiR) nanocomposites with filler contents of 0.001 ∼ 0.005 wt % are prepared to improve electrical tree inhibiting ability under different temperature gradients. The electrical treeing test is performed under three temperature gradients, by controlling the temperature of high voltage and ground sides. Experimental results indicate that the SiR sample with 0.003 wt% graphene presents the best performance on electrical tree resistance. The tree length and accumulated damage are both reduced with the increase of graphene content from 0 to 0.003 wt %, but increased with the further increase of filler content from 0.003 to 0.005 wt %. The tree outline tends to be circular in neat SiR under negative temperature gradient, while is triangular under positive temperature gradient. However, the effect of temperature gradient is weakened when graphene exists. The doping of graphene leads to deeper trap sites at the interfaces between nanoplatelets and polymer matrix, which enhances electrical resistances of SiR. This research provides an effective method to suppress electrical trees of SiR for cable accessories.
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