E. A. Gomaa, M. Diab, A. El-Sonbati, Hamed M Abulenader, A. Helmy
{"title":"用碳玻璃电极(CGE)在KCl水溶液中测定19.1℃时CuCl2与橙G (OG)的相互作用参数","authors":"E. A. Gomaa, M. Diab, A. El-Sonbati, Hamed M Abulenader, A. Helmy","doi":"10.26655/AJNANOMAT.2018.9.3","DOIUrl":null,"url":null,"abstract":"The redox mechanisms were examined for copper chloride in absence and presence of Orange G (OG) at 19.1°C using Carbon glassy electrode (CGE). The supporting electrolyte used is 0.1 M KCl effect of scan rate was also studies for the redox reactions for CuCl2 alone and in presence of the ligand used orange G (OG). Stability constants for the complex formed from the interaction of CuCl2+ Orange G (OG) were evaluated with the different thermo chemical data. Effect of different scan rates were examined for cupric Chloride in absence and presence of the ligand used Orange G (OG).The different scans used are 0.1, 0.05, 0.02 and 0.01 V/Sec. The stability constants and Gibbs free energies of complexation were also estimated for the interaction of CuCl2 with Orange G (OG) in 0.1MKCl supporting electrolyte.","PeriodicalId":8523,"journal":{"name":"Asian Journal of Nanoscience and Materials","volume":"91 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2018-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Interaction Parameters for CuCl2 Plus Orange G (OG) at 19.1oC Using Carbon Glassy Electrode (CGE) in KCl Aqueous Solutions\",\"authors\":\"E. A. Gomaa, M. Diab, A. El-Sonbati, Hamed M Abulenader, A. Helmy\",\"doi\":\"10.26655/AJNANOMAT.2018.9.3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The redox mechanisms were examined for copper chloride in absence and presence of Orange G (OG) at 19.1°C using Carbon glassy electrode (CGE). The supporting electrolyte used is 0.1 M KCl effect of scan rate was also studies for the redox reactions for CuCl2 alone and in presence of the ligand used orange G (OG). Stability constants for the complex formed from the interaction of CuCl2+ Orange G (OG) were evaluated with the different thermo chemical data. Effect of different scan rates were examined for cupric Chloride in absence and presence of the ligand used Orange G (OG).The different scans used are 0.1, 0.05, 0.02 and 0.01 V/Sec. The stability constants and Gibbs free energies of complexation were also estimated for the interaction of CuCl2 with Orange G (OG) in 0.1MKCl supporting electrolyte.\",\"PeriodicalId\":8523,\"journal\":{\"name\":\"Asian Journal of Nanoscience and Materials\",\"volume\":\"91 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2018-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Asian Journal of Nanoscience and Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.26655/AJNANOMAT.2018.9.3\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Asian Journal of Nanoscience and Materials","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.26655/AJNANOMAT.2018.9.3","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
摘要
采用碳玻璃电极(CGE),在19.1℃条件下,研究了无橙G (OG)和有橙G (OG)情况下氯化铜的氧化还原机理。采用0.1 M KCl作为支撑电解质,研究了CuCl2单独和配体为橘色G (OG)时氧化还原反应扫描速率的影响。用不同的热化学数据对CuCl2+橙G (OG)相互作用形成的络合物的稳定性常数进行了评价。用橙色G (OG)考察了不同扫描速率对氯化铜在配体缺失和存在情况下的影响。不同的扫描使用0.1,0.05,0.02和0.01 V/秒。同时计算了CuCl2与橙G (OG)在0.1MKCl负载电解质中相互作用的稳定常数和Gibbs自由能。
Interaction Parameters for CuCl2 Plus Orange G (OG) at 19.1oC Using Carbon Glassy Electrode (CGE) in KCl Aqueous Solutions
The redox mechanisms were examined for copper chloride in absence and presence of Orange G (OG) at 19.1°C using Carbon glassy electrode (CGE). The supporting electrolyte used is 0.1 M KCl effect of scan rate was also studies for the redox reactions for CuCl2 alone and in presence of the ligand used orange G (OG). Stability constants for the complex formed from the interaction of CuCl2+ Orange G (OG) were evaluated with the different thermo chemical data. Effect of different scan rates were examined for cupric Chloride in absence and presence of the ligand used Orange G (OG).The different scans used are 0.1, 0.05, 0.02 and 0.01 V/Sec. The stability constants and Gibbs free energies of complexation were also estimated for the interaction of CuCl2 with Orange G (OG) in 0.1MKCl supporting electrolyte.