催化气化煤油的特性

R. Damayanti, S. Arita, F. Hadiah
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引用次数: 0

摘要

在不同的操作温度和催化剂重量下,对煤的催化气化过程进行了研究。本研究的目的是研究镍钼(NiMo)催化剂气化过程中产生的煤油的特性。研究了不同气化温度(375 ~ 385℃、430 ~ 440℃、475 ~ 485℃)下,添加重量为0%、5%、10%和15%的NiMo催化剂对热值为6400 kcal/kg煤的气化效果。该工艺在常压流化床反应器中进行,空气流量为2升/分钟,运行60分钟。结果表明,在430 ~ 440℃条件下,NiMo作为催化剂对煤的气化效果较好,催化剂质量分数为15%时,生成的煤油收率为9.35%,烃组成为芳烃59.75%、脂肪族26.42%、酚类7.34%。与无催化剂的煤油相比,收率为6.56%,芳烃收率为57.33%,脂肪收率为17.44%,酚收率为16.03%。这表明NiMo催化剂对煤中芳烃和脂肪族烃有较高的选择性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The Characteristic of Coal Oil From Catalytic Coal Gasification
In this work, the catalytic gasification process of coal was studied at different operating temperatures and catalyst weights. The purpose of this study was to study the characteristics of coal oil produced through the gasification process using Nickel Molybdenum (NiMo) catalyst. The effect of adding NiMo catalyst with variations in weight of 0%, 5%, 10% and 15% for different gasification temperatures (375 – 385 °C, 430 – 440 °C, and 475 – 485 °C) were studied on coal with a calorific value of 6,400 kcal/kg. The process was done in fluidized bed reactor under atmospheric pressure and an air flow rate of 2 liters/minute was flow for 60 minutes. The results showed that NiMo is effective as a catalyst in the gasification of coal at 430 – 440 °C, the addition of 15% weight of catalysts produced coal oil with a yield of 9.35% and the composition of hydrocarbon consists of 59.75% of aromatics, 26.42% of aliphatics, and 7.34% of phenolics. Compared to coal oil without catalyst give a yield of 6.56% with 57.33% of aromatics, 17.44% of aliphatics, and 16.03% of phenolics. This showing that NiMo catalysts have a high selectivity to increase aromatic and aliphatic hydrocarbons in coal oil.
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