贵金属(金、铂)-生物聚合物纳米复合材料的抗氧化活性

Shintaro Akiyama, Tomokazu Yoshimura, K. Esumi
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引用次数: 10

摘要

在六氯铂酸和岩藻糖聚糖、海藻酸和透明质酸钠(NaHA)等生物聚合物存在下,通过硼氢化钠还原制备了三种不同的铂-生物聚合物纳米复合材料。随着褐藻糖胶浓度的降低,使用褐藻糖胶制备的铂纳米颗粒的平均粒径逐渐变小,在3.1 ~ 2.6nm之间。另一方面,随着NaHA浓度的降低,使用NaHA制备的铂纳米颗粒的平均粒径略有增大,在3.4nm ~ 3.8nm之间。褐藻酸制备的铂纳米粒子的平均粒径为3.2 ~ 3.4nm,与生物聚合物的浓度无关。采用自旋俘获法研究了铂-生物聚合物纳米复合材料在消除h2o2 / feso4体系中形成的羟基自由基后的抗氧化活性;所有的纳米复合材料都表现出较高的催化活性,这些活性受生物聚合物的浓度和种类的影响。此外,铂-生物聚合物纳米复合材料的活性高于金-生物聚合物纳米复合材料。铂-褐藻酸纳米复合材料的抗氧化活性最高,是抗坏血酸的110倍。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Antioxidant activity of noble metal (gold, platinum)-biopolymer nanocomposites
Three different platinum-biopolymer nanocomposites have been prepared independently in the presence of hexachloroplatinic acid and biopolymers like fucoidan, alginic acid and sodium hyaluronate (NaHA) via sodium borohydride reduction. The average particle diameter of platinum nanoparticles using fucoidan becomes slightly smaller, with a decrease of the concentration of fucoidan, ranging from 3.1 to 2.6nm. On the other hand, the average particle diameter of platinum nanoparticles using NaHA becomes slightly larger, with a decrease of the concentration of NaHA, ranging from 3.4nm to 3.8nm. The average particle diameter of platinum nanoparticles using alginic acid is 3.2-3.4nm which is independent of the biopolymer concentrations. The antioxidant activities of the platinum-biopolymer nanoconiposites upon elimination of hydroxyl radicals formed in an H 2 O 2 /FeSO 4 system have been studied using a spin-trapping method; All the nanocomposites exhibit high catalytic activities that are affected by the concentration and the kind of the biopolymer. In addition, the activities of the platinum-biopolymer nanocomposites are higher than those of the gold biopolymer nanocomposites. The highest antioxidant activity for the platinum-alginic acid nanocomposites was 110 times higher than that of ascorbic acid.
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