Cd3(dppz)2(顺式-chdc)2(反式-chdc)[dppz =二吡啶[3,2-a:2′,3′-c]吩那嗪和chdc = 1,4-环己二羧酸盐]的合成与晶体结构

J. Han, De-li Liu, P. Gao, Ning Li
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引用次数: 0

摘要

合成了配位聚合物Cd3(dppz)2(顺式-chdc)2(反式-chdc) (dppz =二吡啶[3,2-a:2 ',3 ' -c]非那嗪,chdc = 1,4-环己二羧酸盐)(1),分子式为C60H50Cd3N8O12,并通过单晶x射线衍射测定了其晶体结构。该配合物属于三斜体系,空间群P1, a = 8.6338(17) a, b = 10.774(2) a, c = 14.872(3) a, α = 77.23(3)°,β = 81.77(3)°,γ = 82.80(3)°。chdc2-羧酸桥接Cd(II)阳离子,形成罕见的三核Cd(II)簇。顺式chdc2-配体由三核Cd(II)簇结合在一起,形成双链。此外,反式chdc2-配体桥接相邻的双链链,产生一个有趣的二维框架。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and Crystal Structure of Cd3(dppz)2(cis-chdc)2(trans-chdc)[dppz = dipyrido[3,2-a:2′,3′-c]phenazine and chdc = 1,4-cyclohexanedicarboxylate]
The coordination polymer Cd3(dppz)2(cis-chdc)2(trans-chdc) (dppz = dipyrido[3,2-a:2′,3′-c]phenazine and chdc = 1,4-cyclohexanedicarboxylate) (1), with the formula C60H50Cd3N8O12 was synthesized and the crystal structure was determined by single-crystal X-ray diffraction. The complex belongs to a triclinic system, space group P1 with a = 8.6338(17)A, b = 10.774(2)A, c = 14.872(3)A, α = 77.23(3)°, β = 81.77(3)°, γ = 82.80(3)°. The chdc2- carboxylates bridge the Cd(II) cations to form rare trinuclear Cd(II) clusters. The cis-chdc2- ligands are held together by the trinuclear Cd(II) clusters to generate a double-stranded chain. Further, the trans-chdc2- ligands bridge adjacent double-stranded chains to yield an interesting two-dimensional framework.
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