{"title":"影响分子结构的振动频率和强度综合νC腈的N系列的多环芳烃在红外光谱—I","authors":"H.P. Figeys , J. Nasielski","doi":"10.1016/0371-1951(66)80054-1","DOIUrl":null,"url":null,"abstract":"<div><p>This work describes an electronic theory, based on L.C.A.O., of the integrated intensities of localized vibrators in π-electron systems.</p><p>Using this theory, we have shown that the solvation of polycyclic aromatic nitriles (CCl<sub>4</sub>) is partially inhibited by steric effects due to peri hydrogen atoms.</p></div>","PeriodicalId":101180,"journal":{"name":"Spectrochimica Acta","volume":"22 12","pages":"Pages 2055-2063"},"PeriodicalIF":0.0000,"publicationDate":"1966-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0371-1951(66)80054-1","citationCount":"4","resultStr":"{\"title\":\"Influence de la structure moléculaire sur la fréquence et l'intensité intégrée de la vibration νCN d'une serie de nitriles polycycliques aromatiques en spectroscopie infra-rouge—I\",\"authors\":\"H.P. Figeys , J. Nasielski\",\"doi\":\"10.1016/0371-1951(66)80054-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This work describes an electronic theory, based on L.C.A.O., of the integrated intensities of localized vibrators in π-electron systems.</p><p>Using this theory, we have shown that the solvation of polycyclic aromatic nitriles (CCl<sub>4</sub>) is partially inhibited by steric effects due to peri hydrogen atoms.</p></div>\",\"PeriodicalId\":101180,\"journal\":{\"name\":\"Spectrochimica Acta\",\"volume\":\"22 12\",\"pages\":\"Pages 2055-2063\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1966-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0371-1951(66)80054-1\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica Acta\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0371195166800541\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0371195166800541","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Influence de la structure moléculaire sur la fréquence et l'intensité intégrée de la vibration νCN d'une serie de nitriles polycycliques aromatiques en spectroscopie infra-rouge—I
This work describes an electronic theory, based on L.C.A.O., of the integrated intensities of localized vibrators in π-electron systems.
Using this theory, we have shown that the solvation of polycyclic aromatic nitriles (CCl4) is partially inhibited by steric effects due to peri hydrogen atoms.
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