{"title":"三乙酰丙酮铬(III) [Cr(C5H7O2)3(c)]生成焓的量热计算","authors":"M. Pathak, Raghvendu Pathak","doi":"10.22232/stj.2019.07.01.12","DOIUrl":null,"url":null,"abstract":"From thermochemical studies of organometallic compounds, a host of thermodynamic parameters viz., heat capacity, entropy, Gibbs energy etc., can be evaluated. The present communication deals with the evaluation of enthalpy of combustion and thereby estimation of enthalpy of formation of crystalline trisacetylacetonato chromium(III) [Cr (C5H7O2)3 (c)] or [Cr (acac)3 cH) and enthalpy of formation fH° –1 –1 respectively. Experimental data obtained are in good agreement with one another.","PeriodicalId":22107,"journal":{"name":"Silpakorn University Science and Technology Journal","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2019-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Calorimetric Computation of Enthalpy of Formation of Trisacetylacetonato Chromium(III) [Cr(C5H7O2)3(c)]\",\"authors\":\"M. Pathak, Raghvendu Pathak\",\"doi\":\"10.22232/stj.2019.07.01.12\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"From thermochemical studies of organometallic compounds, a host of thermodynamic parameters viz., heat capacity, entropy, Gibbs energy etc., can be evaluated. The present communication deals with the evaluation of enthalpy of combustion and thereby estimation of enthalpy of formation of crystalline trisacetylacetonato chromium(III) [Cr (C5H7O2)3 (c)] or [Cr (acac)3 cH) and enthalpy of formation fH° –1 –1 respectively. Experimental data obtained are in good agreement with one another.\",\"PeriodicalId\":22107,\"journal\":{\"name\":\"Silpakorn University Science and Technology Journal\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Silpakorn University Science and Technology Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.22232/stj.2019.07.01.12\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Silpakorn University Science and Technology Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.22232/stj.2019.07.01.12","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Calorimetric Computation of Enthalpy of Formation of Trisacetylacetonato Chromium(III) [Cr(C5H7O2)3(c)]
From thermochemical studies of organometallic compounds, a host of thermodynamic parameters viz., heat capacity, entropy, Gibbs energy etc., can be evaluated. The present communication deals with the evaluation of enthalpy of combustion and thereby estimation of enthalpy of formation of crystalline trisacetylacetonato chromium(III) [Cr (C5H7O2)3 (c)] or [Cr (acac)3 cH) and enthalpy of formation fH° –1 –1 respectively. Experimental data obtained are in good agreement with one another.