三乙酰丙酮铬(III) [Cr(C5H7O2)3(c)]生成焓的量热计算

M. Pathak, Raghvendu Pathak
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引用次数: 0

摘要

从有机金属化合物的热化学研究,许多热力学参数,即热容,熵,吉布斯能等,可以评估。本文讨论了燃烧焓的计算,从而分别计算了三乙酰丙酮铬(III) [Cr (C5H7O2)3 (c)]或[Cr (acac) 3ch]晶体的生成焓和生成焓fH°-1 -1。得到的实验数据相互吻合良好。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Calorimetric Computation of Enthalpy of Formation of Trisacetylacetonato Chromium(III) [Cr(C5H7O2)3(c)]
From thermochemical studies of organometallic compounds, a host of thermodynamic parameters viz., heat capacity, entropy, Gibbs energy etc., can be evaluated. The present communication deals with the evaluation of enthalpy of combustion and thereby estimation of enthalpy of formation of crystalline trisacetylacetonato chromium(III) [Cr (C5H7O2)3 (c)] or [Cr (acac)3 cH) and enthalpy of formation fH° –1 –1 respectively. Experimental data obtained are in good agreement with one another.
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