钼的稳定同位素地球化学

1区 地球科学 Q1 Earth and Planetary Sciences
B. Kendall, T. Dahl, A. Anbar
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引用次数: 188

摘要

>“这个伟大问题的答案……关于生命、宇宙和万物……> >是……深思带着无比的威严和平静说……> >“我查得非常彻底,”电脑说,“这就是答案。> >——道格拉斯·亚当斯《银河系漫游指南》钼(Mo)是原子序数为42的元素,它具有独特的性质,使它成为地球科学、生命科学和工业中许多问题的答案。在地球科学中,钼的氧化还原敏感性使其在回答有关环境氧化还原条件的问题时特别有用。特别是,它在30多年前首次被认为是海洋古还原度的代用物(Holland 1984;Emerson和Huested, 1991)——在20世纪90年代末和21世纪初,当对现代环境中Mo地球化学行为的理解显著提高时,这一应用最终取得了成果(例如,Crusius等,1996;Helz et al. 1996, 2011;Morford and Emerson 1999;Erickson and Helz 2000;Barling et al. 2001;Siebert et al. 2003, 2005;Arnold et al. 2004;Vorlicek et al. 2004;Morford et al. 2005;Nagler et al. 2005;Algeo and Lyons 2006;McManus et al. 2006;Poulson et al. 2006;Anbar等人,2007;Wille et al. 2007;Pearce et al. 2008;Archer and Vance 2008;Neubert et al. 2008;Scott et al. 2008;Gordon et al. 2009;Poulson Brucker et al. 2009)。在生命科学领域,至少在约20亿年前,随着依赖钼的氮酶的进化,大自然将钼作为应对生物固氮挑战的答案(Boyd等人,2011)。钼也是硝酸还原酶的核心,而硝酸还原酶对吸收和异化硝酸还原至关重要(Glass et al. 2009)。因此,莫是中心……
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The Stable Isotope Geochemistry of Molybdenum
> “The Answer to the Great Question... Of Life, the Universe and Everything... > > Is... Forty-two,” said Deep Thought, with infinite majesty and calm… > > “I checked it very thoroughly,” said the computer, “and that quite definitely is the answer.” > > — Douglas Adams, The Hitchhiker’s Guide to the Galaxy Molybdenum (Mo)—the element with atomic number 42—possesses unique properties that make it the answer to many questions in the geosciences, life sciences, and industry. In the geosciences, the redox sensitivity of Mo makes it particularly useful for answering questions about environmental redox conditions. In particular, it was first suggested as an ocean paleoredox proxy over 30 years ago (Holland 1984; Emerson and Huested 1991)—an application that finally came to fruition in the late 1990s and 2000s when understanding of Mo geochemical behavior in modern environments improved significantly (e.g., Crusius et al. 1996; Helz et al. 1996, 2011; Morford and Emerson 1999; Erickson and Helz 2000; Barling et al. 2001; Siebert et al. 2003, 2005; Arnold et al. 2004; Vorlicek et al. 2004; Morford et al. 2005; Nagler et al. 2005; Algeo and Lyons 2006; McManus et al. 2006; Poulson et al. 2006; Anbar et al. 2007; Wille et al. 2007; Pearce et al. 2008; Archer and Vance 2008; Neubert et al. 2008; Scott et al. 2008; Gordon et al. 2009; Poulson Brucker et al. 2009). In the life sciences, nature settled on Mo as the answer to the challenge of biological-N2 fixation at least ~ 2 billion years ago (Boyd et al. 2011), with the evolution of the Mo-dependent nitrogenase enzyme. Molybdenum is also at the heart of nitrate reductase enzymes, which are essential for assimilatory and dissimilatory nitrate reduction (Glass et al. 2009). Therefore, Mo is central …
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来源期刊
Reviews in Mineralogy & Geochemistry
Reviews in Mineralogy & Geochemistry 地学-地球化学与地球物理
CiteScore
8.30
自引率
0.00%
发文量
39
期刊介绍: RiMG is a series of multi-authored, soft-bound volumes containing concise reviews of the literature and advances in theoretical and/or applied mineralogy, crystallography, petrology, and geochemistry. The content of each volume consists of fully developed text which can be used for self-study, research, or as a text-book for graduate-level courses. RiMG volumes are typically produced in conjunction with a short course but can also be published without a short course. The series is jointly published by the Mineralogical Society of America (MSA) and the Geochemical Society.
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