泡沫聚苯乙烯热解过程产气动力学研究

I. Anom
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引用次数: 0

摘要

本研究旨在研究聚苯乙烯垃圾热解过程中产气的反应动力学。在180°C的恒温条件下,在没有催化剂的情况下对聚苯乙烯泡沫废料进行热解。相比之下,添加沸石催化剂的泡沫聚苯乙烯废料的热解在170℃恒温下进行。本研究样品中使用的泡沫聚苯乙烯废料用量为200克,天然沸石催化剂用量为5克。在180℃恒温条件下,不使用催化剂的泡沫聚苯乙烯废弃物热解生成气体,反应动力学发生在零级。该结果符合Arrhenius方程K = Ae10617/RT,活化能(Ea)为1.27 × 103 kJ.mol-1。在170°C的恒温条件下,通过添加沸石催化剂生成气体,泡沫聚苯乙烯废料的热解也发生在零级。方程为Arrhenius K= ae4711,5 /RT,活化能Ea为5.66x102 kJ.mol-1。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Kinetic Study of Gas Formation in Styrofoam Pyrolysis Process
This research aims to study the reaction kinetics of gas formation in the pyrolysis of styrofoam waste. Pyrolysis of styrofoam waste without a catalyst takes place at a constant temperature of 180°C. In contrast, the pyrolysis of styrofoam waste by adding a zeolite catalyst took place at a constant temperature of 170°C. The amount of styrofoam waste used in this research sample is 200 grams, and the natural zeolite catalyst is 5 grams. Pyrolysis of styrofoam waste without using a catalyst form a gas at a constant temperature of 180°C, the kinetics of the reaction takes place on the zero-order. This result follows the Arrhenius equation K = Ae10617/RT with an activation energy value (Ea) of 1.27x103 kJ.mol-1. Pyrolysis of styrofoam waste by adding a zeolite catalyst to gas formation at a constant temperature of 170°C also takes place on the zero-order. The equation follows Arrhenius K= Ae4711,5/RT and the activation energy value (Ea) is 5.66x102 kJ.mol-1.
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