孔径分布和温度对催化剂扭曲度的影响

S. Sadighi, M. Bahmani, S. R. S. Mohadecy
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引用次数: 4

摘要

研究了放热反应中催化剂球团内部温度梯度和孔径分布对扭曲系数值的影响。采用二维孔隙网络模拟了催化剂颗粒的结构。孔隙网络的物质和能量平衡用有限差分格式进行了书写和离散。对等温球团和非等温球团的弯曲系数进行了比较。估计的扭曲系数随内部颗粒温度梯度和孔径的显著变化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
EFFECT OF PORE SIZE DISTRIBUTION AND TEMPERATURE ON THE CATALYST TORTUOSITY
Effect of temperature gradients, for an exothermic reaction, inside a catalyst pellet and the pore size distribution on the value of tortuosity factor is studied. The structure of the catalyst pellet is simulated using a two dimensional pore network. Material and energy balances for the pore network are written and discretised using a finite difference scheme. Tortuosity factors obtained for the isothermal and non-isothermal pellets are compared. Significant variation of the estimated tortuosity factor with internal particle temperature gradient and pore size is obtained.
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