非等温动力学(1)单一基本过程

T. Ozawa
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引用次数: 7

摘要

利用“广义时间”和“广义速率”的概念,导出了单个初等过程的基本关系。这些概念对于描述只涉及一个基本过程的反应是有用的,并且通过使用这些有用的关系,导出了动力学分析的等转换方法,包括积分法和导数法,并用一些例子解释了这些方法。本文的动力学分析方法和其他描述也适用于单个基本过程的物理变化,如扩散和热激流。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Non-isothermal Kinetics (1) Single Elementary Process
Fundamental relations are derived for a single elementary process by using concepts of "generalized time" and "generalized rate". These concepts are useful for describing reactions in which only a single elementary process is involved, and by using these useful relations isoconversion methods for kinetic analysis, both of integral methods and a derivative method, are derived and explained with some illustrations. The methods for kinetic analysis and other descriptions in this article are also applicable to physical changes of a single elementary process, such as diffusion and thermal stimulated currents.
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