生物柴油废食用油对废聚苯乙烯催化裂化制烃馏分的影响及其在汽油机上的应用

H. Juwono, A. Elliyanti, F. S. Pamungkas, A. Assari, A. Dermawan, A. Nurfitriyah
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引用次数: 0

摘要

采用Al-MCM-41/Ceramic催化裂化法制备了聚苯乙烯废弃物和废食用油生物柴油的液体燃料。采用SEM-EDX、吡啶红外光谱、N2气体吸附-脱附等方法研究了催化剂的结构、形貌、酸度和孔隙度。采用气相色谱-质谱联用技术对催化裂化产物进行了分析。在57% (P): 43% (M)的进料变化条件下,裂解时间为1 h,烃分(< C7)为0.48%,烃分(C8 ~ C12)为20.99%,烃分(> C12)为78.53%,产率最高。物理特性分别以密度、闪点和热值的形式报告。将液体燃料的性能与商用燃料、Premium (RON 88)和添加剂甲基叔丁基醚(MTBE)进行比较,分别为225 (mL): 750 (mL): 18.25 (mL),发动机使用的汽油发电机组在负载2118瓦时的热效率为28.22%。基于这项研究,所有原料的变化产生的液体燃料符合SNI 06-3506-1994关于汽油燃料类型质量的规定。关键词:催化裂化,聚苯乙烯废弃物,废食用油,液体燃料
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Influence of Biodiesel Waste Cooking Oil on Produce Hydrocarbon Fraction by Catalytic Cracking Waste Polystyrene and its Application in Gasoline Engine
Liquid fuel from polystyrene waste and waste cooking oil biodiesel was successfully obtained through catalytic cracking using Al-MCM-41/Ceramic. The structure, morphology, acidity, and porosity of the catalyst were studied by SEM-EDX, pyridine FTIR, and N2 gas adsorption-desorption. The products of catalytic cracking were analyzed using gas chromatogram-mass spectroscopy (GC-MS). The highest yield was obtained at feedstock variations of 57% (P): 43% (M) with the number of hydrocarbon fractions (< C7) is 0.48%, hydrocarbon fraction (C8 - C12) is 20.99%, and hydrocarbon fraction (> C12) is 78.53% in the cracking time 1 hours. Physical characteristics were reported in the form of density, flash point, and caloric value respective. The performance of liquid fuels with commercial fuels, Premium (RON 88), and additives of methyl tertiary butyl ether (MTBE) comparisons of 225 (mL): 750 (mL): 18.25 (mL) respectively produce thermal efficiency on engine use gasoline generator sets was 28.22% at the load of 2118 Watts. Based on this research, all variations of feedstock produce liquid fuels that are in accordance with SNI 06-3506-1994 concerning the quality of gasoline fuel types. Keywords: Catalytic cracking, polystyrene waste, waste cooking oil, liquid fuel
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