{"title":"羰基化合物与三价磷试剂的反应。第一部分:环戊二烯酮","authors":"J. Miller, G. Stevenson, B. C. Williams","doi":"10.1039/J39710002714","DOIUrl":null,"url":null,"abstract":"Tetracyclone and 2-methyl-3,4,5-triphenylcyclopentadienone react with diphenylphosphine oxide and with dimethyl phosphonate to produce a series of 1 : 1 adducts, in which the phosphorus is attached to the α-carbon of the ketones. In addition, dimethyl phosphonate forms adducts resulting from reaction at the carbonyl group of tetracyclone. Detailed physical evidence for the structures of these adducts is presented, and the factors which control their formation are discussed.","PeriodicalId":17245,"journal":{"name":"Journal of The Chemical Society C: Organic","volume":"44 1","pages":"2714-2720"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Reactions of carbonyl compounds with tervalent phosphorus reagents. Part I. Cyclopentadienones\",\"authors\":\"J. Miller, G. Stevenson, B. C. Williams\",\"doi\":\"10.1039/J39710002714\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Tetracyclone and 2-methyl-3,4,5-triphenylcyclopentadienone react with diphenylphosphine oxide and with dimethyl phosphonate to produce a series of 1 : 1 adducts, in which the phosphorus is attached to the α-carbon of the ketones. In addition, dimethyl phosphonate forms adducts resulting from reaction at the carbonyl group of tetracyclone. Detailed physical evidence for the structures of these adducts is presented, and the factors which control their formation are discussed.\",\"PeriodicalId\":17245,\"journal\":{\"name\":\"Journal of The Chemical Society C: Organic\",\"volume\":\"44 1\",\"pages\":\"2714-2720\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society C: Organic\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/J39710002714\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society C: Organic","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/J39710002714","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Reactions of carbonyl compounds with tervalent phosphorus reagents. Part I. Cyclopentadienones
Tetracyclone and 2-methyl-3,4,5-triphenylcyclopentadienone react with diphenylphosphine oxide and with dimethyl phosphonate to produce a series of 1 : 1 adducts, in which the phosphorus is attached to the α-carbon of the ketones. In addition, dimethyl phosphonate forms adducts resulting from reaction at the carbonyl group of tetracyclone. Detailed physical evidence for the structures of these adducts is presented, and the factors which control their formation are discussed.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
