{"title":"Cu-B/烧结碳复合材料界面润湿及力学性能的改善","authors":"Haozi Zuo, Guangning Wu, Xiaobo Li, Zhangli Huang, Wenfu Wei, Zefeng Yang","doi":"10.1109/ICEMPE51623.2021.9509120","DOIUrl":null,"url":null,"abstract":"By copper-alloying with different content of B element forming binary alloy to improve the bonding force between carbon and copper, and the Cu-B/sintered-carbon composites were prepared successfully by gas pressure impregnation. The mechanism of boron on interface enhancement, mechanical and electrical properties of composites was studied. The results showed that the mechanical strength and electrical conductivity were proportion to the boron content, while the contact angle was in inverse proportion to the B content. When the doping amount was 2.5wt%, the flexural strength and electrical conductivity were increased by 65% and 54% respectively compared with composites without modification and the contact angle decreased to 21°. The reason was that the boron carbide with moderate thickness at the interface could enhance the Cu/C interfacial bonding by transforming from physical bonding to chemical bonding. This study proves that the moderate addition of boron can improve the wettability of C/Cu system, which resulting in the improvement of mechanical and electrical properties of Cu-B/ sintered-carbon composites.","PeriodicalId":7083,"journal":{"name":"2021 International Conference on Electrical Materials and Power Equipment (ICEMPE)","volume":"4 1","pages":"1-4"},"PeriodicalIF":0.0000,"publicationDate":"2021-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Improvement of Interfacial Wetting and Mechanical Electrical Properties of Cu-B/ sintered-carbon Composites\",\"authors\":\"Haozi Zuo, Guangning Wu, Xiaobo Li, Zhangli Huang, Wenfu Wei, Zefeng Yang\",\"doi\":\"10.1109/ICEMPE51623.2021.9509120\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"By copper-alloying with different content of B element forming binary alloy to improve the bonding force between carbon and copper, and the Cu-B/sintered-carbon composites were prepared successfully by gas pressure impregnation. The mechanism of boron on interface enhancement, mechanical and electrical properties of composites was studied. The results showed that the mechanical strength and electrical conductivity were proportion to the boron content, while the contact angle was in inverse proportion to the B content. When the doping amount was 2.5wt%, the flexural strength and electrical conductivity were increased by 65% and 54% respectively compared with composites without modification and the contact angle decreased to 21°. The reason was that the boron carbide with moderate thickness at the interface could enhance the Cu/C interfacial bonding by transforming from physical bonding to chemical bonding. This study proves that the moderate addition of boron can improve the wettability of C/Cu system, which resulting in the improvement of mechanical and electrical properties of Cu-B/ sintered-carbon composites.\",\"PeriodicalId\":7083,\"journal\":{\"name\":\"2021 International Conference on Electrical Materials and Power Equipment (ICEMPE)\",\"volume\":\"4 1\",\"pages\":\"1-4\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-04-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"2021 International Conference on Electrical Materials and Power Equipment (ICEMPE)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/ICEMPE51623.2021.9509120\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"2021 International Conference on Electrical Materials and Power Equipment (ICEMPE)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/ICEMPE51623.2021.9509120","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
摘要
通过在铜中加入不同含量的B元素,形成二元合金,提高碳与铜的结合力,并通过气压浸渍法制备了Cu-B/烧结碳复合材料。研究了硼对复合材料界面增强、力学性能和电学性能的作用机理。结果表明,复合材料的机械强度和电导率与硼含量成正比,而接触角与硼含量成反比。当掺杂量为2.5wt%时,复合材料的抗弯强度和电导率分别比未改性的复合材料提高了65%和54%,接触角减小到21°。其原因是界面处厚度适中的碳化硼可以增强Cu/C界面的结合,由物理结合转变为化学结合。本研究证明,适量添加硼可以改善C/Cu体系的润湿性,从而改善Cu- b /烧结碳复合材料的力学性能和电性能。
Improvement of Interfacial Wetting and Mechanical Electrical Properties of Cu-B/ sintered-carbon Composites
By copper-alloying with different content of B element forming binary alloy to improve the bonding force between carbon and copper, and the Cu-B/sintered-carbon composites were prepared successfully by gas pressure impregnation. The mechanism of boron on interface enhancement, mechanical and electrical properties of composites was studied. The results showed that the mechanical strength and electrical conductivity were proportion to the boron content, while the contact angle was in inverse proportion to the B content. When the doping amount was 2.5wt%, the flexural strength and electrical conductivity were increased by 65% and 54% respectively compared with composites without modification and the contact angle decreased to 21°. The reason was that the boron carbide with moderate thickness at the interface could enhance the Cu/C interfacial bonding by transforming from physical bonding to chemical bonding. This study proves that the moderate addition of boron can improve the wettability of C/Cu system, which resulting in the improvement of mechanical and electrical properties of Cu-B/ sintered-carbon composites.