复合催化剂Co2B/TiO2对NaBH4水解的影响

Yong Li, Yuxin Zhang, Yuxing Gu, Yufei Cai, Ruizhu Zhang, Xueping Zheng
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引用次数: 1

摘要

为了提高NaBH4的氢释放能力,研究了不同摩尔比和百分比组成的Co2B和TiO2化合物催化NaBH4的产氢性能。实验主要集中在产氢速率和产氢体积上。结果表明,当Co2B/TiO2的比例和用量不明显时,NaBH4的释氢效果不明显。改变配比和用量,NaBH4水解释氢量在343375ml之间。然而,对氢气释放速率的研究发现,复合催化剂的比例和用量对氢气释放速率的影响非常显著。Co2B/TiO2的添加量在1 ~ 4%之间时,催化剂样品的氢释放率明显提高。在所有复合催化剂样品中,Co2B/2TiO2含量为5%的样品氢释放速率最大。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effects of Composite Catalyst Co2B/TiO2 on Hydrolysis of NaBH4
For the purpose of improving hydrogen release capacity of NaBH4, hydrogen generation performance of NaBH4 was catalyzed by Co2B and TiO2 compound with different mole ratio and percentage composition are investigated. The experiment mainly concentrated in the hydrogen generation rate and the hydrogen generation volume. The results indicate that the effects of hydrogen release of NaBH4 when the proportions and amount of Co2B/TiO2 are not obvious. Changing the proportions and the amount, the amount of hydrogen release by hydrolysis of NaBH4 are between 343375ml. However, the study on the rate of hydrogen release finds that the effects of the proportion and amount of the compound catalyst on the rate of hydrogen release are very marked. The rate of hydrogen release of the catalyst samples presents an obvious increase when the amount of Co2B/TiO2 is between 1-4%. Among all the samples of compound catalyst, the rate of hydrogen release of the sample with 5% Co2B/2TiO2 is the largest.
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