{"title":"252cf -等离子解吸质谱的碎片化。1. 酸的正离子","authors":"R.A. Zingaro, A.G. Vindiola, J.H. Zoeller Jr.","doi":"10.1016/0020-7381(83)85129-8","DOIUrl":null,"url":null,"abstract":"<div><p>Positive ions observed in the <sup>252</sup>Cf Plasma Desorption Mass Spectrum of behenic acid occur at masses consistent with several cations and cation radical derivatives. Fragmentation mechanisms are suggested by the disparate populations of alkyl, allyl, acyl, ketene and olefinic ions.</p></div>","PeriodicalId":13998,"journal":{"name":"International Journal of Mass Spectrometry and Ion Physics","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1983-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0020-7381(83)85129-8","citationCount":"3","resultStr":"{\"title\":\"Fragmentation in 252Cf-plasma desorption mass spectrometry. 1. Positive ions of behenic acid\",\"authors\":\"R.A. Zingaro, A.G. Vindiola, J.H. Zoeller Jr.\",\"doi\":\"10.1016/0020-7381(83)85129-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Positive ions observed in the <sup>252</sup>Cf Plasma Desorption Mass Spectrum of behenic acid occur at masses consistent with several cations and cation radical derivatives. Fragmentation mechanisms are suggested by the disparate populations of alkyl, allyl, acyl, ketene and olefinic ions.</p></div>\",\"PeriodicalId\":13998,\"journal\":{\"name\":\"International Journal of Mass Spectrometry and Ion Physics\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1983-09-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0020-7381(83)85129-8\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Mass Spectrometry and Ion Physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0020738183851298\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Mass Spectrometry and Ion Physics","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0020738183851298","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Fragmentation in 252Cf-plasma desorption mass spectrometry. 1. Positive ions of behenic acid
Positive ions observed in the 252Cf Plasma Desorption Mass Spectrum of behenic acid occur at masses consistent with several cations and cation radical derivatives. Fragmentation mechanisms are suggested by the disparate populations of alkyl, allyl, acyl, ketene and olefinic ions.