252cf -等离子解吸质谱的碎片化。1. 酸的正离子

R.A. Zingaro, A.G. Vindiola, J.H. Zoeller Jr.
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引用次数: 3

摘要

在252Cf等离子体解吸质谱中观察到的正离子出现在与几个阳离子和阳离子自由基衍生物一致的质量上。由不同种群的烷基、烯丙基、酰基、烯酮和烯烃离子提出了断裂机制。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Fragmentation in 252Cf-plasma desorption mass spectrometry. 1. Positive ions of behenic acid

Positive ions observed in the 252Cf Plasma Desorption Mass Spectrum of behenic acid occur at masses consistent with several cations and cation radical derivatives. Fragmentation mechanisms are suggested by the disparate populations of alkyl, allyl, acyl, ketene and olefinic ions.

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