Ahmed M. Donia★, E. El-Shereafy, Mohamed A. El-Ries
{"title":"coii -和cuii -二甲双胍配合物的固态热异构化","authors":"Ahmed M. Donia★, E. El-Shereafy, Mohamed A. El-Ries","doi":"10.1016/0168-7336(90)80002-2","DOIUrl":null,"url":null,"abstract":"<div><p>The biologically active square planar Co<sup>II</sup>- and Cu<sup>II</sup>-metformin complexes show a phase change upon heating in the solid state. This phase change was studied by various analytical and spectral methods and some kinetic parameters of the transformation reaction calculated. The obtained phase change was also discussed in terms of solid state thermal isomerisation.</p></div>","PeriodicalId":101061,"journal":{"name":"Reactivity of Solids","volume":"8 1","pages":"Pages 1-7"},"PeriodicalIF":0.0000,"publicationDate":"1990-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0168-7336(90)80002-2","citationCount":"5","resultStr":"{\"title\":\"Solid state thermal isomerisation of CoII-and CuII-metformin complexes\",\"authors\":\"Ahmed M. Donia★, E. El-Shereafy, Mohamed A. El-Ries\",\"doi\":\"10.1016/0168-7336(90)80002-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The biologically active square planar Co<sup>II</sup>- and Cu<sup>II</sup>-metformin complexes show a phase change upon heating in the solid state. This phase change was studied by various analytical and spectral methods and some kinetic parameters of the transformation reaction calculated. The obtained phase change was also discussed in terms of solid state thermal isomerisation.</p></div>\",\"PeriodicalId\":101061,\"journal\":{\"name\":\"Reactivity of Solids\",\"volume\":\"8 1\",\"pages\":\"Pages 1-7\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1990-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0168-7336(90)80002-2\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Reactivity of Solids\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0168733690800022\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reactivity of Solids","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0168733690800022","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Solid state thermal isomerisation of CoII-and CuII-metformin complexes
The biologically active square planar CoII- and CuII-metformin complexes show a phase change upon heating in the solid state. This phase change was studied by various analytical and spectral methods and some kinetic parameters of the transformation reaction calculated. The obtained phase change was also discussed in terms of solid state thermal isomerisation.