萜类化合物的天然产物化学-致敬帕维尔·弗拉德院士的卓越遗产

IF 0.5 Q4 CHEMISTRY, MULTIDISCIPLINARY

Chemistry Journal of Moldova Pub Date : 2021-06-01 DOI:10.19261/cjm.2021.856

A. Aricu

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引用次数: 1

摘要

本文的目的是简要介绍Pavel Vlad院士及其弟子在萜类天然产物化学领域的一些最有价值的科学贡献。在Pavel Vlad院士的指导和直接贡献下，设计了确定一系列labdanic二萜的绝对构型并将其转化为双环、三环和四环化合物的新方法。Pavel Vlad院士提出了由1,4-乙二醇合成四氢呋喃、叔醇乙酸酯合成烯烃以及不饱和环酮光脱氢合成二烯酮的通用新方法。

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The Natural Product Chemistry of Terpenoids - a Tribute to the Remarkable Legacy of Academician Pavel Vlad

The purpose of this paper is to put forward concisely some of the most valuable scientific contributions of academician Pavel Vlad and his disciples to the field of natural product chemistry of terpenoids. Under the guidance and with direct contribution of academician Pavel Vlad, new approaches to determining the absolute configuration of a series of labdanic diterpenoids and of converting them into bi-, tri- and tetra- cyclic compounds have been designed. Novel universal methods for synthesizing tetrahydrofurans from 1,4-glycols, olefins from tertiary alcoholic acetates, as well as dienones by means of photodehydrogenation of unsaturated cyclic ketons have been developed by academician Pavel Vlad.

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来源期刊

Chemistry Journal of Moldova CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

0.90

自引率

20.00%

发文量

审稿时长

12 weeks

期刊介绍： "Chemistry Journal of Moldova. General, Industrial and Ecological Chemistry" seeks to publish experimental or theoretical research results of outstanding significance and timeliness in all fields of Chemistry, including Industrial and Ecological Chemistry. The main goal of this edition is strengthening the Chemical Society of Moldova, following development of research in Moldovan chemical institutions and promotion of their collaboration with international chemical community. Manuscripts are welcome from all countries.