{"title":"2 -溴- 4,5 -二甲基苯酚与二氟化氙的氟化反应","authors":"H. Koudstaal, C. Olieman","doi":"10.1002/RECL.19811000609","DOIUrl":null,"url":null,"abstract":"Fluorination of 2-bromo-4,5-dimethylphenol (1) with xenon difluoride, using boron trifluoride etherate as catalyst, gave 2-bromo-4,5-dimethyl-4-fluorocyclohexa-2,5-dienone (2), 2-bromo-3,4-dimethyl-6-fluorophenol (3) and 6-bromo-3,4-dimethyl-2-fluorophenol (4). The products were isolated by means of preparative reverse-phase HPLC and identified by 1H and 13C NMR spectroscopy.","PeriodicalId":20823,"journal":{"name":"Recueil des Travaux Chimiques des Pays-Bas","volume":"13 1","pages":"246-248"},"PeriodicalIF":0.0000,"publicationDate":"2010-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fluorination of 2‐bromo‐4,5‐dimethylphenol with xenon difluoride\",\"authors\":\"H. Koudstaal, C. Olieman\",\"doi\":\"10.1002/RECL.19811000609\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Fluorination of 2-bromo-4,5-dimethylphenol (1) with xenon difluoride, using boron trifluoride etherate as catalyst, gave 2-bromo-4,5-dimethyl-4-fluorocyclohexa-2,5-dienone (2), 2-bromo-3,4-dimethyl-6-fluorophenol (3) and 6-bromo-3,4-dimethyl-2-fluorophenol (4). The products were isolated by means of preparative reverse-phase HPLC and identified by 1H and 13C NMR spectroscopy.\",\"PeriodicalId\":20823,\"journal\":{\"name\":\"Recueil des Travaux Chimiques des Pays-Bas\",\"volume\":\"13 1\",\"pages\":\"246-248\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2010-09-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Recueil des Travaux Chimiques des Pays-Bas\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/RECL.19811000609\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Recueil des Travaux Chimiques des Pays-Bas","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/RECL.19811000609","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Fluorination of 2‐bromo‐4,5‐dimethylphenol with xenon difluoride
Fluorination of 2-bromo-4,5-dimethylphenol (1) with xenon difluoride, using boron trifluoride etherate as catalyst, gave 2-bromo-4,5-dimethyl-4-fluorocyclohexa-2,5-dienone (2), 2-bromo-3,4-dimethyl-6-fluorophenol (3) and 6-bromo-3,4-dimethyl-2-fluorophenol (4). The products were isolated by means of preparative reverse-phase HPLC and identified by 1H and 13C NMR spectroscopy.
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