利用电纺钇掺杂SnO2纳米纤维合成高选择性室温操作氨传感器

Utkarsh Nirbhay, Ajay Beniwal, S. Lalwani, Sunny
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引用次数: 0

摘要

成功合成了掺杂钇(Y)的SnO2纳米纤维,并将其用于检测室温下的低浓度氨。采用静电纺丝-煅烧法制备了不同Y掺杂浓度的SnO2纳米纤维,其中Y掺杂浓度为$5 wt$。% Y掺杂SnO2纳米纤维(平均直径~90 nm)表现出最好的响应。为了分析该传感器的选择性,我们还研究了该传感器对丙酮、甲醇、乙醇以及氨等其他分析物的传感性能。在10ppm的氨浓度下,该传感器的响应率为237%,分别是10ppm时丙酮(87.5%)、乙醇(44.4%)和甲醇(36%)的2.7倍、5.3倍和6.6倍,这说明该传感器对氨的检测具有良好的选择性。制造的传感器具有快速响应和恢复时间,即不到一分钟。采用x射线衍射仪(XRD)和扫描电镜(SEM)对Y掺杂SnO2纳米纤维的结构和形态特征进行了表征。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Highly selective room temperature operated ammonia sensor synthesized using electrospun yttrium doped SnO2 nanofibers
Yttrium (Y) doped SnO2 nanofibers were successfully synthesized and used for detecting low ammonia concentrations at room temperature (RT). Electrospinning followed by calcination method was used to synthesize the Y doped SnO2 nanofibers for various Y concentrations, among which $5 wt$.% Y doped SnO2 nanofibers (average diameter ~90 nm) demonstrated the best response. To analyze the selectivity of the sensor, the sensing properties were also studied for other analytes like acetone, methanol and ethanol, along with ammonia. The% response was observed to be 237%under 10 ppm of ammonia, which is found to be 2.7, 5.3 and 6.6 times higher as compared to acetone (87.5%), ethanol (44.4%) and methanol (36%) responses at 10 ppm, respectively, defining the excellent selectivity of the sensor towards ammonia detection. The fabricated sensor manifests fast response and recovery times i.e. less than a minute. The structural and morphological characteristics of Y doped SnO2 nanofibers were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively.
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