埋地API 5L X65钢储罐CNTs/环氧树脂纳米复合涂层的力学和防腐性能

IF 1.2 Q3 MULTIDISCIPLINARY SCIENCES
A. S. Buhari, A. Abdulrahman, S. A. Lawal, A. Abdulkareem, R. A. Muriana, J. Tijani, H. K. Ibrahim, Yusuf Olanrewaju Busari
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引用次数: 0

摘要

将石油产品储存在地下金属罐中以确保安全是常见的做法。然而,这些储罐的完整性可能因土壤腐蚀而受到损害,从而造成经济和环境后果。本研究考察了碳纳米管在钢罐上的机械和防腐能力(CNTs)和环氧树脂涂层。腐蚀离子的存在、电阻率和pH值都在土壤样品中进行了测试。碳纳米管以1.5%,2.5%,3.5%和4.5%的环氧树脂的重量比例混合来制造涂层。采用高分辨率扫描电镜(HRSEM)和能量色散x射线能谱(EDX)设备研究了未涂层钢、环氧树脂和CNTs/环氧树脂涂层钢试样的形貌。采用电化学阻抗谱(EIS)进行腐蚀分析,建立形貌分析结果。土壤样品的平均离子含量为氯化物272 mg/kg,硫酸盐467.20 mg/kg,平均电阻率为167.40 Ω-m。样品的pH值是酸性的,因为它在6.11-7.48之间。加入CNTs的环氧树脂的抗拉强度、硬度和抗拉模量随CNTs的增加而增加。添加3.5% CNTs对复合材料机械强度的影响最好。根据EIS的调查,纳米复合涂层表现出相当优异的导体性能。因此,环氧树脂和碳纳米管的杂化提高了涂层表面的疏水性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Mechanical and Corrosion Protection Characteristics of CNTs/epoxy resin Nanocomposite Coating on Buried API 5L X65 Steel Storage Tank
The storage of petroleum products in buried metal tanks to ensure safety is common practice. However, the integrity of these tanks could be compromised by soil corrosion with economic and environmental consequences. This study examines carbon nanotubes mechanical and anti-corrosive capabilities (CNTs) and epoxy resin coating on steel tanks. The presence of corrosive ions, resistivity, and pH values were all tested in the soil sample. CNT was mixed in proportions of 1.5, 2.5, 3.5 and 4.5 weight percent of epoxy resin to create the coatings. The morphology of uncoated steel, epoxy, and CNTs/ epoxy resin-coated steel specimens was studied using high-resolution scanning electron microscopy (HRSEM) equipment with energy dispersive x-ray spectroscopy (EDX). Electrochemical impedance spectroscopy (EIS) was used for corrosion analysis, and the morphological result was established. The average ions content soil samples showed 272 mg/kg chloride, 467.20 mg/kg sulphate and 167.40 Ω-m for the average resistivity value. The sample’s pH was acidic because it fell within 6.11–7.48. The tensile strength, hardness, and tensile modulus of epoxy resin with CNTs increase with CNTs. The addition of 3.5% CNTs has the best effect on the mechanical strength of the composite. The nanocomposite coatings exhibited considerably superior conductors, according to the EIS investigation. Thus, the hybrid of epoxy and CNTs increases the hydrophobicity of the coated surface.
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来源期刊
Journal of Physical Science
Journal of Physical Science Physics and Astronomy-Physics and Astronomy (all)
CiteScore
1.70
自引率
0.00%
发文量
19
期刊介绍: The aim of the journal is to disseminate latest scientific ideas and findings in the field of physical sciences among scientists in Malaysia and international regions. This journal is devoted to the publication of articles dealing with research works in Chemistry, Physics and Engineering. Review articles will also be considered. Manuscripts must be of scientific value and will be submitted to independent referees for review. Contributions must be written in English and must not have been published elsewhere.
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