氧化锌/氧化石墨烯纳米复合材料:合成、表征及其光学性能

Avinash R. Kachere, Prashant M. Kakade, Archana R. Kanwade, Priyanka Dani, Nandkumar T. Mandlik, Sachin R. Rondiya, N. Dzade, S. Jadkar, S. Bhosale
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引用次数: 15

摘要

本研究采用简单高效的水热法制备了高品质氧化锌(ZnO)和氧化石墨烯(GO)纳米复合材料(ZnO/GO纳米复合材料)。采用沉淀法和改进Hummer法分别合成了氧化锌和氧化石墨烯。同样,研究了不同浓度氧化石墨烯对ZnO纳米粒子结构和光学性质的影响。用x射线衍射(XRD)和拉曼光谱对样品进行了结构表征。这些结构表征技术表明ZnO/GO纳米复合材料中存在ZnO、GO和相关元素的特征峰。扫描电镜显示,部分球形氧化锌纳米颗粒与氧化石墨烯纳米片反应形成氧化锌纳米棒,并形成还原氧化石墨烯(r-GO)。紫外可见光谱和光致发光光谱结果表明,氧化石墨烯浓度对ZnO/GO纳米复合材料的光学性能有影响。在纯ZnO样品中观察到ZnO/GO纳米复合材料的光学带隙缩小。ZnO/GO纳米复合材料所表现出的光学性能的改善,使其适用于UV-Vis光电子器件和光催化应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Zinc Oxide/Graphene Oxide Nanocomposites: Synthesis, Characterization and Their Optical Properties
In this research, the synthesis of high-quality zinc oxide (ZnO) and graphene oxide (GO) nanocomposite (ZnO/GO nanocomposite) was carried out using the simple and efficient hydrothermal method. The ZnO and GO were separately synthesised by using the precipitation and modified Hummer’s method, respectively. Likewise, the effects of different concentrations of GO on the structural and optical properties of ZnO nanoparticles were investigated. All the desired samples were structurally characterized by X-ray diffraction (XRD) and Raman spectroscopy. Those structural characterised techniques indicate the presence of characteristic peaks of ZnO, GO and related elements in the ZnO/GO nanocomposite. Scanning electron microscopy showed that some portions of the spherical shaped ZnO nanoparticles reacted with GO nanosheets to form ZnO nanorods with the formation of reduced graphene oxide (r-GO). UV-Visible and photoluminescence spectroscopy revealed that the optical properties of the ZnO/GO nanocomposite were affected by the GO concentration. The narrowing of optical band gap in the ZnO/GO nanocomposite was observed to pure ZnO sample. The improved optical properties displayed by the ZnO/GO nanocomposites makes them suitable for applications like UV-Vis optoelectronics devices and photocatalytic applications.
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