{"title":"自然层状Aurivillius相:多铁材料设计的柔性支架","authors":"J. Halpin, L. Keeney","doi":"10.23647/ca.md20202905","DOIUrl":null,"url":null,"abstract":"The Aurivillius layer-structures, described by the general formula Bi2O2(Am-1BmO3m+1), are naturally 2-dimensionally nanostructured. They are very flexible frameworks for a wide variety of applications, given that different types of cations can beaccommodated both at the A- and B-sites. In this review article, we describe how the Aurivillius phases are a particularly attractive class of oxides for the design of prospective single phase multiferroic systems for multi-state data storage applications, as they offer the potential to include substantial amounts of magnetic cations within a strongly ferroelectric system. The ability to vary m yields differing numbers of symmetrically distinct B-site locations over which the magnetic cations can be distributed and generates driving forces for cation partitioning and magnetic ordering. We discuss how out-of-phase boundary and stacking fault defects can further influence local stoichiometry and the extent of cation partitioning in these intriguing material systems.","PeriodicalId":19388,"journal":{"name":"OAJ Materials and Devices","volume":"42 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2021-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Naturally Layered Aurivillius Phases: Flexible Scaffolds for the Design of Multiferroic Materials\",\"authors\":\"J. Halpin, L. Keeney\",\"doi\":\"10.23647/ca.md20202905\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The Aurivillius layer-structures, described by the general formula Bi2O2(Am-1BmO3m+1), are naturally 2-dimensionally nanostructured. They are very flexible frameworks for a wide variety of applications, given that different types of cations can beaccommodated both at the A- and B-sites. In this review article, we describe how the Aurivillius phases are a particularly attractive class of oxides for the design of prospective single phase multiferroic systems for multi-state data storage applications, as they offer the potential to include substantial amounts of magnetic cations within a strongly ferroelectric system. The ability to vary m yields differing numbers of symmetrically distinct B-site locations over which the magnetic cations can be distributed and generates driving forces for cation partitioning and magnetic ordering. We discuss how out-of-phase boundary and stacking fault defects can further influence local stoichiometry and the extent of cation partitioning in these intriguing material systems.\",\"PeriodicalId\":19388,\"journal\":{\"name\":\"OAJ Materials and Devices\",\"volume\":\"42 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2021-01-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"OAJ Materials and Devices\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.23647/ca.md20202905\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"OAJ Materials and Devices","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.23647/ca.md20202905","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Naturally Layered Aurivillius Phases: Flexible Scaffolds for the Design of Multiferroic Materials
The Aurivillius layer-structures, described by the general formula Bi2O2(Am-1BmO3m+1), are naturally 2-dimensionally nanostructured. They are very flexible frameworks for a wide variety of applications, given that different types of cations can beaccommodated both at the A- and B-sites. In this review article, we describe how the Aurivillius phases are a particularly attractive class of oxides for the design of prospective single phase multiferroic systems for multi-state data storage applications, as they offer the potential to include substantial amounts of magnetic cations within a strongly ferroelectric system. The ability to vary m yields differing numbers of symmetrically distinct B-site locations over which the magnetic cations can be distributed and generates driving forces for cation partitioning and magnetic ordering. We discuss how out-of-phase boundary and stacking fault defects can further influence local stoichiometry and the extent of cation partitioning in these intriguing material systems.